Rare earth element geochemistry of the Upper Permian limestone: the Kanigorgeh mining district, NW Iran

Ali ABEDINI; Ali Asghar CALAGARI

Makale detayları

Rare earth element geochemistry of the Upper Permian limestone: the Kanigorgeh mining district, NW Iran

Yazarlar:

Ali ABEDINI | Ali Asghar CALAGARI

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Earth Sciences 2015 Vol.24 Issue 4

Belge Tipi:

Makale

Yayın Tarihi:

8/2015

Belge Dili:

Türkçe

Document ID (Org No.):

2000731456

Sıklık:

İki Aylık

eISSN:

1303-619X

pISSN:

1300-0985

Özet:

 

The limestone of the Ruteh Formation of Upper Permian age in the Kanigorgeh district (northeast of Bukan, NW Iran) contains several layers and lenses of bauxitic ores. Mineralogical data show that this limestone consists of calcite and quartz as major and plagioclase, kaolinite, and hematite as minor mineral phases. Geochemical analyses reveal that the proportions of ?REEs (La-Lu) in this limestone vary from 35.28 to 160.78 ppm. The values of Eu and Ce anomalies (normalized to PAAS) of the limestone have ranges of 1.11-1.68 and 0.89-1.16, respectively. The high values of ?REEs; low values of Y/Ho; strong and positive correlations between ?REEs and elements such as Si, Al, Ti, V, Co, Ni, Rb, Cu, and Nb; and negative correlations between CaO and ?REEs suggest that the observed variations in values of ?REEs in the limestone were controlled principally by the quantity of detrital materials. Geochemical data also illustrate that the observed positive Eu anomalies in the limestone may be due to the presence of plagioclase and also a function of diagenetic processes. Furthermore, the variations in Ce anomalies may be due to the detrital input. The distribution of REEs (normalized to chondrite) illustrates different patterns in both rocks (the limestone and the bauxitic ores) in light of differentiation degree of LREEs from HREEs and values of conservative indexes such as Eu anomaly. Considering these pronounced discrepancies, it appears that the limestone, despite having relatively high concentration of ?REEs, did not play a significant role in supplying lanthanides for the bauxitic ores.

 

The limestone of the Ruteh Formation of Upper Permian age in the Kanigorgeh district (northeast of Bukan, NW Iran) contains several layers and lenses of bauxitic ores. Mineralogical data show that this limestone consists of calcite and quartz as major and plagioclase, kaolinite, and hematite as minor mineral phases. Geochemical analyses reveal that the proportions of ?REEs (La-Lu) in this limestone vary from 35.28 to 160.78 ppm. The values of Eu and Ce anomalies (normalized to PAAS) of the limestone have ranges of 1.11-1.68 and 0.89-1.16, respectively. The high values of ?REEs; low values of Y/Ho; strong and positive correlations between ?REEs and elements such as Si, Al, Ti, V, Co, Ni, Rb, Cu, and Nb; and negative correlations between CaO and ?REEs suggest that the observed variations in values of ?REEs in the limestone were controlled principally by the quantity of detrital materials. Geochemical data also illustrate that the observed positive Eu anomalies in the limestone may be due to the presence of plagioclase and also a function of diagenetic processes. Furthermore, the variations in Ce anomalies may be due to the detrital input. The distribution of REEs (normalized to chondrite) illustrates different patterns in both rocks (the limestone and the bauxitic ores) in light of differentiation degree of LREEs from HREEs and values of conservative indexes such as Eu anomaly. Considering these pronounced discrepancies, it appears that the limestone, despite having relatively high concentration of ?REEs, did not play a significant role in supplying lanthanides for the bauxitic ores.

Makale detayları

Rare earth element geochemistry of the Upper Permian limestone: the Kanigorgeh mining district, NW Iran

Yazarlar: Ali ABEDINI | Ali Asghar CALAGARI

Yayıncı: TUBITAK

Dergi: Turkish Journal of Earth Sciences 2015 Vol.24 Issue 4

Belge Tipi: Makale

Yayın Tarihi: 8/2015

Belge Dili: Türkçe

Document ID (Org No.): 2000731456

Sıklık: İki Aylık

eISSN: 1303-619X

pISSN: 1300-0985

Sayı

Yazarlar:

Ali ABEDINI | Ali Asghar CALAGARI

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Earth Sciences 2015 Vol.24 Issue 4

Belge Tipi:

Makale

Yayın Tarihi:

8/2015

Belge Dili:

Türkçe

Document ID (Org No.):

2000731456

Sıklık:

İki Aylık

eISSN:

1303-619X

pISSN:

1300-0985