SYNTHESIS, CRYSTAL STRUCTURE, MAGNETIC PROPERTY, AND N2-GAS-ADSORPTION PROPERTY OF DINUCLEAR COPPER(II) 3,4,5-TRIMETHOXYBENZOATE

Masahiro Mikuriya; Chihiro Yamakawa; Kensuke TANABE; Daisuke YOSHİOKA; Ryoji MİTSUHASHİ; Hidekazu TANAKA; Makoto HANDA

doi:https://doi.org/10.18596/jotcsa.370793

Makale detayları

SYNTHESIS, CRYSTAL STRUCTURE, MAGNETIC PROPERTY, AND N2-GAS-ADSORPTION PROPERTY OF DINUCLEAR COPPER(II) 3,4,5-TRIMETHOXYBENZOATE

Yazarlar:

Masahiro Mikuriya | Chihiro Yamakawa | Kensuke TANABE | Daisuke YOSHİOKA | Ryoji MİTSUHASHİ | Hidekazu TANAKA | Makoto HANDA

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 1, pp.103-110

Belge Tipi:

Makale

Yayın Tarihi:

12/2017

Belge Dili:

İngilizce

Document ID (Org No.):

2000503330

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.370793

Özet:

 


 Copper(II) 3,4,5-trimethoxybenzoate, [Cu2(3,4,5-(CH3O)3C6H2CO2)4 (CH3OH)2]·2DMF, was prepared and characterized by elemental analysis, infrared and UV-vis spectra and temperature dependence of magnetic susceptibilities (4.5—300 K). The crystal structure was determined by the single-crystal X-ray diffraction method. It crystallizes in the triclinic space group P1(_) with a = 8.2110(13) Å, b = 13.181(2) Å, c = 13.409(2) Å, α = 97.967(3)°, β = 102.378(3)°, γ = 105.009(3)°, V = 1339.8(4) Å3, Dx = 1.465 g/cm3, and Z = 1. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0363 and 0.0816, respectively, for all 5991 independent reflections. The crystal contains crystallographically centrosymmetric dinuclear molecule with axial methanol molecules and crystal DMF molecules [Cu···Cu 2.6190(6) Å]. Magnetic susceptibility data show a considerable antiferromagnetic interaction between the two copper(II) ions (2J = –292 cm–1). Gas-adsorption behavior was investigated for N2.

.

Makale detayları

SYNTHESIS, CRYSTAL STRUCTURE, MAGNETIC PROPERTY, AND N2-GAS-ADSORPTION PROPERTY OF DINUCLEAR COPPER(II) 3,4,5-TRIMETHOXYBENZOATE

Yazarlar: Masahiro Mikuriya | Chihiro Yamakawa | Kensuke TANABE | Daisuke YOSHİOKA | Ryoji MİTSUHASHİ | Hidekazu TANAKA | Makoto HANDA

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Kimya mühendisliği

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 1, pp.103-110

Belge Tipi: Makale

Yayın Tarihi: 12/2017

Belge Dili: İngilizce

Document ID (Org No.): 2000503330

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.370793

Sayı

Yazarlar:

Masahiro Mikuriya | Chihiro Yamakawa | Kensuke TANABE | Daisuke YOSHİOKA | Ryoji MİTSUHASHİ | Hidekazu TANAKA | Makoto HANDA

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 1, pp.103-110

Belge Tipi:

Makale

Yayın Tarihi:

12/2017

Belge Dili:

İngilizce

Document ID (Org No.):

2000503330

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.370793