Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives

William I. AWAD

doi:https://doi.org/10.1501/Commub_0000000517

Makale detayları

Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives

Yazarlar:

William I. AWAD

Yayıncı:

Ankara University

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 1983 Vol.29, pp.0-0

Belge Tipi:

Makale

Yayın Tarihi:

12/1982

Belge Dili:

İngilizce

Document ID (Org No.):

2000710522

Sıklık:

İki Yıllık

eISSN:

2687-4806

pISSN:

1303-6017

DOI:

https://doi.org/10.1501/Commub_0000000517

Özet:

 

Diethyl (2-bromo-l- phenyl, vinyl) phosphonite and diethyl (1-chloro-l-phenyl, vinyl) phosphonate react with diazomethane, diphenyldiazomethane, and phenylbenzoyldiazomet- hane. The reaction with diazomethane goes by 3 ' 2 “ 5 scheme of dipolar cycloaddition. The reaction of the phosphonite with diphenyldiazomethane goes by the 3-3-6 scheme, while in the case of phosphonate cleavage of C-P bond took place. However, the reaction of phospho-nate with pheriylbenzoyldiazomethane goes by 3 -- 2 — 5 scheme of 1, 3-dipolar cycloaddition with. the cleavage of C-P bond. .

Makale detayları

Reaction Of Unsaturated ^-Bromo Phosphonite And a-Chloro Phosphonate With DiazoMethane And Its Derivatives

Yazarlar: William I. AWAD

Yayıncı: Ankara University

Ana Başlıklar: Kimya mühendisliği

Dergi: Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 1983 Vol.29, pp.0-0

Belge Tipi: Makale

Yayın Tarihi: 12/1982

Belge Dili: İngilizce

Document ID (Org No.): 2000710522

Sıklık: İki Yıllık

eISSN: 2687-4806

pISSN: 1303-6017

DOI: https://doi.org/10.1501/Commub_0000000517

Sayı

Yazarlar:

William I. AWAD

Yayıncı:

Ankara University

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering 1983 Vol.29, pp.0-0

Belge Tipi:

Makale

Yayın Tarihi:

12/1982

Belge Dili:

İngilizce

Document ID (Org No.):

2000710522

Sıklık:

İki Yıllık

eISSN:

2687-4806

pISSN:

1303-6017

DOI:

https://doi.org/10.1501/Commub_0000000517