Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones

Nevroz ASLAN ERTAŞ; Arif KIVRAK

Makale detayları

Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones

Yazarlar:

Nevroz ASLAN ERTAŞ | Arif KIVRAK

Yayıncı:

Kyrgyz-Turkish Manas University

Ana Başlıklar:

Uygulamalı fizik

Dergi:

MANAS Journal of Engineering 2020 Vol.8 Issue 1, pp.22-27

Belge Tipi:

Makale

Yayın Tarihi:

6/2020

Belge Dili:

İngilizce

Document ID (Org No.):

2000527889

Sıklık:

İki Yıllık

eISSN:

1694-7398

pISSN:

1694-7398

Özet:

 

In general, Suzuki-Miyaura coupling reaction between aryl bromide and arylboronic acids form the new C-C bond in the presence of Pd-catalyst. In the present study, 2-bromo-3-ferrocenyl-1,4-naphthoquinone 2 intermediate is synthesized by starting from 2,3-dibromo-1,4-naphthoquinone via Suzuki-Miyaura Coupling reaction. Then, it is investigated that the reaction between 2 and arylboronic acids give a new rearrangement reaction involving free radicals. Ferrocene structure displays critical roles for the formation of 2,3-diaryl-1,4-naphthoquinones. This reaction could be first example for the radical C-C bond cleavage reactions including ferrocene.

Makale detayları

Ferrocene as a leaving group; Unexpected rearrangement reactions for the synthesis of 2,3-diarylnapthoquinones

Yazarlar: Nevroz ASLAN ERTAŞ | Arif KIVRAK

Yayıncı: Kyrgyz-Turkish Manas University

Ana Başlıklar: Uygulamalı fizik

Dergi: MANAS Journal of Engineering 2020 Vol.8 Issue 1, pp.22-27

Belge Tipi: Makale

Yayın Tarihi: 6/2020

Belge Dili: İngilizce

Document ID (Org No.): 2000527889

Sıklık: İki Yıllık

eISSN: 1694-7398

pISSN: 1694-7398

Sayı

Yazarlar:

Nevroz ASLAN ERTAŞ | Arif KIVRAK

Yayıncı:

Kyrgyz-Turkish Manas University

Ana Başlıklar:

Uygulamalı fizik

Dergi:

MANAS Journal of Engineering 2020 Vol.8 Issue 1, pp.22-27

Belge Tipi:

Makale

Yayın Tarihi:

6/2020

Belge Dili:

İngilizce

Document ID (Org No.):

2000527889

Sıklık:

İki Yıllık

eISSN:

1694-7398

pISSN:

1694-7398