Synthesis and computational studies of new metallo-phthalocyanines bearing   dibenzoxanthenes and evaluation of their optical properties in solution and   solid PMMA/ZnPc/Al nanocomposite films

Ali Reza KARIMI; Zeinab JAFARZADEH; Meysam SOURINIA; Akbar ZENDEHNAM; Azam KHODADADI; Zeinab DALIRNASAB; Mohammad SOLIMANNEJAD; Peyman ZOLGHARNEIN

Makale detayları

Synthesis and computational studies of new metallo-phthalocyanines bearing dibenzoxanthenes and evaluation of their optical properties in solution and solid PMMA/ZnPc/Al nanocomposite films

Yazarlar:

Ali Reza KARIMI | Zeinab JAFARZADEH | Meysam SOURINIA | Akbar ZENDEHNAM | Azam KHODADADI | Zeinab DALIRNASAB | Mohammad SOLIMANNEJAD | Peyman ZOLGHARNEIN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2016 Vol.40 Issue 4, pp.602-612

Belge Tipi:

Makale

Yayın Tarihi:

7/2016

Belge Dili:

Türkçe

Document ID (Org No.):

2000726579

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

New thermally stable metallo-phthalocyanines bearing   dibenzoxanthenes as highly organo-solubilizing aromatic hydrocarbon   substituents were successfully prepared by cyclotetramerization of   corresponding phthalonitriles with anhydrous metal salts   [Zn(CH33_{3}COO)22_{2} and NiCl22_{2}] in the presence of a catalytic amount   of DBU in 2-(dimethylamino) ethanol. All of these phthalocyanines are soluble   in some organic solvents such as DMF, DMSO, THF, CH22_{2}Cl22_{2}, and   CHCl33_{3}. Then we successfully prepared the poly(methyl methacrylate)   (PMMA)/ZnPc/Al nanocomposite films by incorporating Al nanoparticles into a   transparent PMMA/ZnPc matrix. The structure and morphology of nanocomposite   films were studied using X-ray diffraction and scanning electron microscopy.   The optical absorption spectra of PMMA/ZnPc/Al nanocomposite films showed   red shifting in the Q-band in the polymeric matrix. The geometrical   structure of two phthalocyanines was investigated at the RHF/3-21G*   computational level.

Makale detayları

Synthesis and computational studies of new metallo-phthalocyanines bearing dibenzoxanthenes and evaluation of their optical properties in solution and solid PMMA/ZnPc/Al nanocomposite films

Yazarlar: Ali Reza KARIMI | Zeinab JAFARZADEH | Meysam SOURINIA | Akbar ZENDEHNAM | Azam KHODADADI | Zeinab DALIRNASAB | Mohammad SOLIMANNEJAD | Peyman ZOLGHARNEIN

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2016 Vol.40 Issue 4, pp.602-612

Belge Tipi: Makale

Yayın Tarihi: 7/2016

Belge Dili: Türkçe

Document ID (Org No.): 2000726579

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Ali Reza KARIMI | Zeinab JAFARZADEH | Meysam SOURINIA | Akbar ZENDEHNAM | Azam KHODADADI | Zeinab DALIRNASAB | Mohammad SOLIMANNEJAD | Peyman ZOLGHARNEIN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2016 Vol.40 Issue 4, pp.602-612

Belge Tipi:

Makale

Yayın Tarihi:

7/2016

Belge Dili:

Türkçe

Document ID (Org No.):

2000726579

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527