Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity

Mahameed Ameen; Fadia Ahmed

Makale detayları

Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity

Yazarlar:

Mahameed Ameen | Fadia Ahmed

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Transition Metal Chemistry | Biochemistry and Cell Biology (Other)

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.10 Issue 4, pp.975-984

Belge Tipi:

Makale

Yayın Tarihi:

11/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001294241

pISSN:

2149-0120

Anahtar kelimeler:

Özet:

 This research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions NiII, CuII, and ZnII and through the interaction with ligand potassium decyl xanthate and complexes of formula MDEXANT2 were prepared: M NiII, CuII, and ZnII, and then the interaction of these complexes with Lewis bidentate bases, to give complexes with the formula MDEXANT2.L, where L 1,10-phenanthroline, 8-hydroxyquinoline, and 2,2-bipyridine. The prepared complexes were characterized by melting point, atomic absorption spectrometry, micro elemental analysis, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, molar electrical conductivity, electronic absorption spectra, and magnetic susceptibility measurements. Magnetic moment and electronic spectra indicated that the complexes of type MDEXANT2 had a tetrahedral geometry, while complexes of type MDEXANT2.L had an octahedral geometry. The conductivity measurements proved the non-electrolytic behavior of all compounds. The biological evaluation against bacterial species indicated that the xanthate complexes were effective against all bacterial types.

 This research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions NiII, CuII, and ZnII and through the interaction with ligand potassium decyl xanthate and complexes of formula MDEXANT2 were prepared: M NiII, CuII, and ZnII, and then the interaction of these complexes with Lewis bidentate bases, to give complexes with the formula MDEXANT2.L, where L 1,10-phenanthroline, 8-hydroxyquinoline, and 2,2-bipyridine. The prepared complexes were characterized by melting point, atomic absorption spectrometry, micro elemental analysis, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, molar electrical conductivity, electronic absorption spectra, and magnetic susceptibility measurements. Magnetic moment and electronic spectra indicated that the complexes of type MDEXANT2 had a tetrahedral geometry, while complexes of type MDEXANT2.L had an octahedral geometry. The conductivity measurements proved the non-electrolytic behavior of all compounds. The biological evaluation against bacterial species indicated that the xanthate complexes were effective against all bacterial types.

 This research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions NiII, CuII, and ZnII and through the interaction with ligand potassium decyl xanthate and complexes of formula MDEXANT2 were prepared: M NiII, CuII, and ZnII, and then the interaction of these complexes with Lewis bidentate bases, to give complexes with the formula MDEXANT2.L, where L 1,10-phenanthroline, 8-hydroxyquinoline, and 2,2-bipyridine. The prepared complexes were characterized by melting point, atomic absorption spectrometry, micro elemental analysis, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, molar electrical conductivity, electronic absorption spectra, and magnetic susceptibility measurements. Magnetic moment and electronic spectra indicated that the complexes of type MDEXANT2 had a tetrahedral geometry, while complexes of type MDEXANT2.L had an octahedral geometry. The conductivity measurements proved the non-electrolytic behavior of all compounds. The biological evaluation against bacterial species indicated that the xanthate complexes were effective against all bacterial types.

 This research includes the synthesis and characterization of twelve new complexes of mono nuclear xanthate for a number of transition metal ions NiII, CuII, and ZnII and through the interaction with ligand potassium decyl xanthate and complexes of formula MDEXANT2 were prepared: M NiII, CuII, and ZnII, and then the interaction of these complexes with Lewis bidentate bases, to give complexes with the formula MDEXANT2.L, where L 1,10-phenanthroline, 8-hydroxyquinoline, and 2,2-bipyridine. The prepared complexes were characterized by melting point, atomic absorption spectrometry, micro elemental analysis, infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, molar electrical conductivity, electronic absorption spectra, and magnetic susceptibility measurements. Magnetic moment and electronic spectra indicated that the complexes of type MDEXANT2 had a tetrahedral geometry, while complexes of type MDEXANT2.L had an octahedral geometry. The conductivity measurements proved the non-electrolytic behavior of all compounds. The biological evaluation against bacterial species indicated that the xanthate complexes were effective against all bacterial types.

Makale detayları

Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity

Yazarlar:

Mahameed Ameen | Fadia Ahmed

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Transition Metal Chemistry | Biochemistry and Cell Biology (Other)

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.10 Issue 4, pp.975-984

Belge Tipi:

Makale

Yayın Tarihi:

11/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001294241

pISSN:

2149-0120

Xanthate

Complexes

Nickel(II)

Copper(II)

Zinc(II)

Biological Activity

Sayı

Makale detayları

Preparation and Characterization of Some Complexes of Nickel(II), Copper (II), and Zinc (II) With Decylxanthate and their Adducts with Nitrogen Base Ligands, and their Biological Activity

Yazarlar: Mahameed Ameen | Fadia Ahmed

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Transition Metal Chemistry | Biochemistry and Cell Biology (Other)

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry Vol.10 Issue 4, pp.975-984

Belge Tipi: Makale

Yayın Tarihi: 11/2023

Belge Dili: İngilizce

Document ID (Org No.): 2001294241

pISSN: 2149-0120

Xanthate

Complexes

Nickel(II)

Copper(II)

Zinc(II)

Biological Activity

Sayı

Yazarlar:

Mahameed Ameen | Fadia Ahmed

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Transition Metal Chemistry | Biochemistry and Cell Biology (Other)

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.10 Issue 4, pp.975-984

Belge Tipi:

Makale

Yayın Tarihi:

11/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001294241

pISSN:

2149-0120