Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline

Asuman UÇAR; Mükerrem FINDIK; Nuriye KOÇAK; Alper ÇOLAK; Onur ŞAHİN

doi:https://doi.org/10.17776/csj.812164

Makale detayları

Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline

Yazarlar:

Asuman UÇAR | Mükerrem FINDIK | Nuriye KOÇAK | Alper ÇOLAK | Onur ŞAHİN

Ana Başlıklar:

Kimya ve ilgili bilimler

Dergi:

Cumhuriyet Science Journal 2021 Vol.42 Issue 1, pp.22-29

Belge Tipi:

Makale

Yayın Tarihi:

3/2021

Belge Dili:

İngilizce

Document ID (Org No.):

2000920284

DOI:

https://doi.org/10.17776/csj.812164

Özet:

 

Herein a novel inorganic-organic hybrid Keggin-type heteropolymolybdate [Ni2Na(C12H8N2)4(BMo12O40)(H2O)2] (1) has been synthesized under hydrothermal conditions in aqueous solution. The cyrstal structure was fully characterized by powder X-ray diffraction (XRD), elemental analysis, Fourier-tranform infrared spectrum (FT-IR), Thermogravimetric analysis (TGA) and Scanning Electron Microscopy (SEM) analysis. Single crystal X-ray structural analysis demonstrates that the complex consists of a Keggin anion [BMo12O40]5− polyanion, four 1,10-phenanthroline (C12H8N2) ligands, two Ni(II) ions, two Na(I) ions and two aqua ligands. The experimental powder X-ray diffraction (XRD) result of the crystal is consistent with the calculated data. The SEM image shows that the compound crystals have a cubic structure.

Makale detayları

Hydrothermal synthesis and crystal structures of a novel Keggin-type polyoxometalate based on 1,10-phenanthroline

Yazarlar: Asuman UÇAR | Mükerrem FINDIK | Nuriye KOÇAK | Alper ÇOLAK | Onur ŞAHİN

Ana Başlıklar: Kimya ve ilgili bilimler

Dergi: Cumhuriyet Science Journal 2021 Vol.42 Issue 1, pp.22-29

Belge Tipi: Makale

Yayın Tarihi: 3/2021

Belge Dili: İngilizce

Document ID (Org No.): 2000920284

DOI: https://doi.org/10.17776/csj.812164

Sayı

Yazarlar:

Asuman UÇAR | Mükerrem FINDIK | Nuriye KOÇAK | Alper ÇOLAK | Onur ŞAHİN

Ana Başlıklar:

Kimya ve ilgili bilimler

Dergi:

Cumhuriyet Science Journal 2021 Vol.42 Issue 1, pp.22-29

Belge Tipi:

Makale

Yayın Tarihi:

3/2021

Belge Dili:

İngilizce

Document ID (Org No.):

2000920284

DOI:

https://doi.org/10.17776/csj.812164