Synthesis and Electrohemical Properties of New Tetra-2-(4-benzyloxyphenyl)ethanol Substituted Metal Free and Metallophthalocyanines

Rıza Bayrak; Ümit Demirbaş; Zekeriya Bıyıklıoğlu; Hakkı Türker Akçay; Halit Kantekin

Makale detayları

Synthesis and Electrohemical Properties of New Tetra-2-(4-benzyloxyphenyl)ethanol Substituted Metal Free and Metallophthalocyanines

Yazarlar:

Rıza Bayrak | Ümit Demirbaş | Zekeriya Bıyıklıoğlu | Hakkı Türker Akçay | Halit Kantekin

Yayıncı:

KCST Founding Board

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Karadeniz Chemical Science and Technology 2018 Issue 2, pp.22-26

Belge Tipi:

Makale

Yayın Tarihi:

6/2018

Belge Dili:

İngilizce

Document ID (Org No.):

2000822052

Sıklık:

İki Yıllık

eISSN:

2636-8560

Özet:

 


The
novel dinitrile compound (3) and peripherally tetra
2-(4-benzyloxyphenyl)ethanol substituted metal-free (4), zinc(II) (5),
cobalt(II) (6) and copper(II) (7) phthalocyanines were synthesized and
characterizated for the first time in this study. Electrochemical
characterization of metal-free and metallophthallocyanines were determined by
using cyclic voltammetry (CV) and square wave voltammetry (SWV) techniques. Metal-free and metallophthalocyanines having
redox inactive centers (Zn+2, Cu+2) showed similar Pc
based electron transfer processes. On the other hand, CoII metal ion
behaves as redox active cations in the core of the Co- phthalocyanine.
Therefore, Co- phthalocyanine gives one metal based reduction reaction
[CoIIPc-2] / [CoIPc-2]-1.

.

Makale detayları

Synthesis and Electrohemical Properties of New Tetra-2-(4-benzyloxyphenyl)ethanol Substituted Metal Free and Metallophthalocyanines

Yazarlar: Rıza Bayrak | Ümit Demirbaş | Zekeriya Bıyıklıoğlu | Hakkı Türker Akçay | Halit Kantekin

Yayıncı: KCST Founding Board

Ana Başlıklar: Kimya mühendisliği

Dergi: Karadeniz Chemical Science and Technology 2018 Issue 2, pp.22-26

Belge Tipi: Makale

Yayın Tarihi: 6/2018

Belge Dili: İngilizce

Document ID (Org No.): 2000822052

Sıklık: İki Yıllık

eISSN: 2636-8560

Sayı

Yazarlar:

Rıza Bayrak | Ümit Demirbaş | Zekeriya Bıyıklıoğlu | Hakkı Türker Akçay | Halit Kantekin

Yayıncı:

KCST Founding Board

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Karadeniz Chemical Science and Technology 2018 Issue 2, pp.22-26

Belge Tipi:

Makale

Yayın Tarihi:

6/2018

Belge Dili:

İngilizce

Document ID (Org No.):

2000822052

Sıklık:

İki Yıllık

eISSN:

2636-8560