Synthetic strategies towards the carbenoid reactions of  ;  -acetylenic carbonyls

Füsun Şeyma KIŞKAN; Emre ÖZGÜZ; Olcay ANAÇ; Nurdan TARAKÇI; Gökçe MEREY

Makale detayları

Synthetic strategies towards the carbenoid reactions of ; -acetylenic carbonyls

Yazarlar:

Füsun Şeyma KIŞKAN | Emre ÖZGÜZ | Olcay ANAÇ | Nurdan TARAKÇI | Gökçe MEREY

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2018 Vol.42 Issue 5, pp.1384-1397

Belge Tipi:

Makale

Yayın Tarihi:

10/2018

Belge Dili:

İngilizce

Document ID (Org No.):

2000726010

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 


 
                         Catalytic reactions of α,βα,βα,β α  ,  β  α,β\alpha ,\beta -conjugated 
carbonyl compounds have been a practical tool towards the synthesis of 
different useful heterocyclic compounds. Despite the numerous reactions with 
carbon-carbon double bond conjugated carbonyls, reactions of acetylenic 
carbonyls are limited. In this study, efficient dioxole synthesis was 
carried out via acetylenic aldehydes and butadiene formation was preferred 
over cyclopropene formation via acetylenic esters as different functional 
groups on these substrates change the product distribution. Both reaction 
conditions (such as solvent and temperature) and electrophilic structure of 
metal carbenoids alter the product distribution; acceptor (A), 
donor-acceptor (DA), and acceptor-acceptor (AA) functionalized diazo 
compounds yield different product types over different mechanisms.
                    

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Makale detayları

Synthetic strategies towards the carbenoid reactions of ; -acetylenic carbonyls

Yazarlar: Füsun Şeyma KIŞKAN | Emre ÖZGÜZ | Olcay ANAÇ | Nurdan TARAKÇI | Gökçe MEREY

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2018 Vol.42 Issue 5, pp.1384-1397

Belge Tipi: Makale

Yayın Tarihi: 10/2018

Belge Dili: İngilizce

Document ID (Org No.): 2000726010

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Füsun Şeyma KIŞKAN | Emre ÖZGÜZ | Olcay ANAÇ | Nurdan TARAKÇI | Gökçe MEREY

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2018 Vol.42 Issue 5, pp.1384-1397

Belge Tipi:

Makale

Yayın Tarihi:

10/2018

Belge Dili:

İngilizce

Document ID (Org No.):

2000726010

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527