Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles

Salih GÜNNAZ

doi:https://doi.org/10.18466/cbayarfbe.632188

Makale detayları

Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles

Yazarlar:

Salih GÜNNAZ

Yayıncı:

Celal Bayar University

Dergi:

Celal Bayar University Journal of Science 2019 Vol.15 Issue 4, pp.351-356

Belge Tipi:

Makale

Yayın Tarihi:

12/2019

Belge Dili:

İngilizce

Document ID (Org No.):

2000705984

Sıklık:

Üç Aylık

eISSN:

1305-1385

pISSN:

1305-130X

DOI:

https://doi.org/10.18466/cbayarfbe.632188

Özet:

 


In this study, bis-benzimidazole
ligands (1a-d) were synthesized using linker groups and they were
evaluated as catalyst generated in situ
from [RuCl2(p-cymene)]2 for transfer hydrogenation (TH) of
acetophenone. The bimetallic Ru (II) arene complex (2b) synthesized from
ligand 1b which showed the best activity among the ligands in the catalytic
TH reaction. The obtained ligands and 2b complex were characterized by 1H-
and 13C-NMR, elemental analysis and IR spectroscopy. The catalytic
activities of complexes having different chain lengths and Y (CH3 or
H) groups were compared. The highest conversion (99%) was obtained with 2b.


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Makale detayları

Synthesis and catalytic activities of bimetallic Ru (II) arene complexes bearing bis-benzimidazoles

Yazarlar: Salih GÜNNAZ

Yayıncı: Celal Bayar University

Dergi: Celal Bayar University Journal of Science 2019 Vol.15 Issue 4, pp.351-356

Belge Tipi: Makale

Yayın Tarihi: 12/2019

Belge Dili: İngilizce

Document ID (Org No.): 2000705984

Sıklık: Üç Aylık

eISSN: 1305-1385

pISSN: 1305-130X

DOI: https://doi.org/10.18466/cbayarfbe.632188

Sayı

Yazarlar:

Salih GÜNNAZ

Yayıncı:

Celal Bayar University

Dergi:

Celal Bayar University Journal of Science 2019 Vol.15 Issue 4, pp.351-356

Belge Tipi:

Makale

Yayın Tarihi:

12/2019

Belge Dili:

İngilizce

Document ID (Org No.):

2000705984

Sıklık:

Üç Aylık

eISSN:

1305-1385

pISSN:

1305-130X

DOI:

https://doi.org/10.18466/cbayarfbe.632188