Production of Silver Nanoparticles Embedded in Pectin/p(HEMA-co-AAc) Hydrogels with Parthenocissus Quinquefolia L Plant Extracts as a Green Synthesis Method

Mehmet Rıza Kıvanç; Alper Önder; Ferah Cömert Önder; Pınar Ilgın

Makale detayları

Production of Silver Nanoparticles Embedded in Pectin/p(HEMA-co-AAc) Hydrogels with Parthenocissus Quinquefolia L Plant Extracts as a Green Synthesis Method

Yazarlar:

Mehmet Rıza Kıvanç | Alper Önder | Ferah Cömert Önder | Pınar Ilgın

Yayıncı:

Çanakkale Onsekiz Mart University

Ana Başlıklar:

Kimya Mühendisliği

Dergi:

Lapseki Meslek Yüksekokulu Uygulamalı Araştırmalar Dergisi Vol.4 Issue 7, pp.12-19

Belge Tipi:

Makale

Yayın Tarihi:

6/2023

Belge Dili:

Türkçe

Document ID (Org No.):

2001295414

pISSN:

2717-8285

Anahtar kelimeler:

Özet:

 PectinpHEMA-co-AAcAgNP nanocomposite hydrogels were developed with a simple, cost-effective and environmentally friendly process. First, pectinpHEMA-co-AAc hydrogels was synthesized with pectin as grafting backbone, 2-hydroxyethyl methacrylate and acrylic acid HEMA and AAc monomers, N,N-methylenebisacrylamide MBA crosslinker and ammonium persulfate APS - N,N,N,N -tetramethyl ethylenediamine TEMED a redox initiator pair by free radical polymerization. The chemical structure and surface properties of pectinpHEMA-co-AAc hydrogels were elucidated by Fourier transform infrared spectroscopy FTIR and scanning electron microscopy SEM. Next, silver ions were incorporated into the hydrogel matrix and pectinpHEMA-co-AAcAgNP nanocomposite hydrogel was developed by in situ reduction of silver ions Ag to silver nanoparticles using Parthenocissus Quinquefolia L leaf extract. The size of AgNPs of nanocomposite hydrogels were determined by characterizing with a transmission electron microscope TEM. Finally, the antimicrobial and antifungal activities of the obtained nanocomposite hydrogels was performed by disk diffusion method using Bacillus Cereus gram-positive, Escherichia Coli gram-negative, bacterial species and Candida albicans as fungal species.

 PectinpHEMA-co-AAcAgNP nanocomposite hydrogels were developed with a simple, cost-effective and environmentally friendly process. First, pectinpHEMA-co-AAc hydrogels was synthesized with pectin as grafting backbone, 2-hydroxyethyl methacrylate and acrylic acid HEMA and AAc monomers, N,N-methylenebisacrylamide MBA crosslinker and ammonium persulfate APS - N,N,N,N -tetramethyl ethylenediamine TEMED a redox initiator pair by free radical polymerization. The chemical structure and surface properties of pectinpHEMA-co-AAc hydrogels were elucidated by Fourier transform infrared spectroscopy FTIR and scanning electron microscopy SEM. Next, silver ions were incorporated into the hydrogel matrix and pectinpHEMA-co-AAcAgNP nanocomposite hydrogel was developed by in situ reduction of silver ions Ag to silver nanoparticles using Parthenocissus Quinquefolia L leaf extract. The size of AgNPs of nanocomposite hydrogels were determined by characterizing with a transmission electron microscope TEM. Finally, the antimicrobial and antifungal activities of the obtained nanocomposite hydrogels was performed by disk diffusion method using Bacillus Cereus gram-positive, Escherichia Coli gram-negative, bacterial species and Candida albicans as fungal species.

 PectinpHEMA-co-AAcAgNP nanocomposite hydrogels were developed with a simple, cost-effective and environmentally friendly process. First, pectinpHEMA-co-AAc hydrogels was synthesized with pectin as grafting backbone, 2-hydroxyethyl methacrylate and acrylic acid HEMA and AAc monomers, N,N-methylenebisacrylamide MBA crosslinker and ammonium persulfate APS - N,N,N,N -tetramethyl ethylenediamine TEMED a redox initiator pair by free radical polymerization. The chemical structure and surface properties of pectinpHEMA-co-AAc hydrogels were elucidated by Fourier transform infrared spectroscopy FTIR and scanning electron microscopy SEM. Next, silver ions were incorporated into the hydrogel matrix and pectinpHEMA-co-AAcAgNP nanocomposite hydrogel was developed by in situ reduction of silver ions Ag to silver nanoparticles using Parthenocissus Quinquefolia L leaf extract. The size of AgNPs of nanocomposite hydrogels were determined by characterizing with a transmission electron microscope TEM. Finally, the antimicrobial and antifungal activities of the obtained nanocomposite hydrogels was performed by disk diffusion method using Bacillus Cereus gram-positive, Escherichia Coli gram-negative, bacterial species and Candida albicans as fungal species.

 PektinpHEMA-ko-AAcAgNP nanokompozit hidrojeller basit, uygun maliyetli ve çevre dostu bir işlemle geliştirilmiştir. İlk olarak pektinpHEMA-ko-AAc hidrojeller, aşılama omurgası olarak pektin, 2-hidroksietil metakrilat ve akrilik asit HEMA ve AAc monomerleri, N,N- metilenbisakrilamid MBA çapraz bağlayıcısı ve amonyum persülfat APS - N,N,N,N-tetrametil etilendiamin TEMED redoks başlatıcı çifti ile serbest radikal polimerizasyonu yoluyla sentezlendi. PektinpHEMA-ko-AAc hidrojellerinin kimyasal yapısı Fourier dönüşümü kızılötesi spektroskopisi FTIR ve yüzey özellikleri taramalı elektron mikroskobu SEM ile aydınlatıldı. Daha sonra, gümüş iyonları hidrojel matrisine dahil edildi ve gümüş nanopartiküller, Parthenocissus Quinquefolia L yaprak özütü kullanılarak gümüş iyonlarının Ag yerinde indirgenmesiyle pektinpHEMA-ko-AAcAgNP nanokompozit hidrojeli geliştirildi. Hazırlanan nanokompozit hidrojeli geçirimli elektron mikroskobu TEM ile karakterize edilerek AgNPlerin boyutu belirlendi. Son olarak, elde edilen nanokompozit hidrojellerin antimikrobiyal aktivitesi Bacillus Cereus gram-pozitif ve Escherichia Coli gram-negatif bakteri türleri üzerine yapılırken, antifungus etkisi ise Candida albicans fungusu üzerine disk difüzyon yöntemi kullanılarak yapılmıştır.

Makale detayları

Production of Silver Nanoparticles Embedded in Pectin/p(HEMA-co-AAc) Hydrogels with Parthenocissus Quinquefolia L Plant Extracts as a Green Synthesis Method

Yazarlar:

Mehmet Rıza Kıvanç | Alper Önder | Ferah Cömert Önder | Pınar Ilgın

Yayıncı:

Çanakkale Onsekiz Mart University

Ana Başlıklar:

Kimya Mühendisliği

Dergi:

Lapseki Meslek Yüksekokulu Uygulamalı Araştırmalar Dergisi Vol.4 Issue 7, pp.12-19

Belge Tipi:

Makale

Yayın Tarihi:

6/2023

Belge Dili:

Türkçe

Document ID (Org No.):

2001295414

pISSN:

2717-8285

Hydrogel

Silver Nanoparticles

Parthenocissus Quinquefolia L

Green SynthesisHidrojel

Gümüş Nanopartiküller

Parthenocissus Quinquefolia L

Yeşil Sentez

Sayı

Makale detayları

Yazarlar: Mehmet Rıza Kıvanç | Alper Önder | Ferah Cömert Önder | Pınar Ilgın

Yayıncı: Çanakkale Onsekiz Mart University

Ana Başlıklar: Kimya Mühendisliği

Dergi: Lapseki Meslek Yüksekokulu Uygulamalı Araştırmalar Dergisi Vol.4 Issue 7, pp.12-19

Belge Tipi: Makale

Yayın Tarihi: 6/2023

Belge Dili: Türkçe

Document ID (Org No.): 2001295414

pISSN: 2717-8285

Sayı

Yazarlar:

Mehmet Rıza Kıvanç | Alper Önder | Ferah Cömert Önder | Pınar Ilgın

Yayıncı:

Çanakkale Onsekiz Mart University

Ana Başlıklar:

Kimya Mühendisliği

Dergi:

Lapseki Meslek Yüksekokulu Uygulamalı Araştırmalar Dergisi Vol.4 Issue 7, pp.12-19

Belge Tipi:

Makale

Yayın Tarihi:

6/2023

Belge Dili:

Türkçe

Document ID (Org No.):

2001295414

pISSN:

2717-8285