Oxovanadium(IV) template derived from benzophenone S-allyl thiosemicarbazone: Synthesis, crystal structure, antioxidant activity and electrochemistry

Berat İLHAN CEYLAN

doi:https://doi.org/10.18596/jotcsa.911318

Makale detayları

Oxovanadium(IV) template derived from benzophenone S-allyl thiosemicarbazone: Synthesis, crystal structure, antioxidant activity and electrochemistry

Yazarlar:

Berat İLHAN CEYLAN

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

İnorganik kimya

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2021 Vol.8 Issue 2, pp.593-608

Belge Tipi:

Makale

Yayın Tarihi:

5/2021

Belge Dili:

İngilizce

Document ID (Org No.):

2000502355

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.911318

Özet:

 

The oxovanadium(IV) template was formed with the reaction between vanadyl sulfate pentahydrate, 2-hydroxybenzophenone-S-allylthiosemicarbazone, and 3-methoxysalicylaldehyde. The synthesized template complex, along with the starting ligand, was subjected to UV-Vis, FTIR, mass, and magnetic measurement. The square pyramidal structure was proven with the single-crystal X-ray diffraction method. Stronger crystals were formed with π-π interactions, which was also supported by the corresponding peak in the mass spectrum. Conventional three-electrode electrochemistry was performed and cyclic voltammetry revealed that complex 2 underwent one-electron reduction (VIVO –VIIIO) and one-electron oxidation (VIVO –VVO) at the vanadium center. The total antioxidant capacity of the template compound and the starting ligand was performed by the CUPRAC method, yielding that the complex was more potent than the control compound, ascorbic acid.

Makale detayları

Oxovanadium(IV) template derived from benzophenone S-allyl thiosemicarbazone: Synthesis, crystal structure, antioxidant activity and electrochemistry

Yazarlar: Berat İLHAN CEYLAN

Yayıncı: Turkish Chemical Society

Ana Başlıklar: İnorganik kimya

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2021 Vol.8 Issue 2, pp.593-608

Belge Tipi: Makale

Yayın Tarihi: 5/2021

Belge Dili: İngilizce

Document ID (Org No.): 2000502355

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.911318

Sayı

Yazarlar:

Berat İLHAN CEYLAN

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

İnorganik kimya

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2021 Vol.8 Issue 2, pp.593-608

Belge Tipi:

Makale

Yayın Tarihi:

5/2021

Belge Dili:

İngilizce

Document ID (Org No.):

2000502355

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.911318