Synthesis And Characterization of Multidentate Schiff Bases Containing s-Triazine: Investigation of Their Some Transition Metal Complexes

Erdem Büyükaslan; Ahmed Hamdi Mirghani; Şaban Uysal

Makale detayları

Synthesis And Characterization of Multidentate Schiff Bases Containing s-Triazine: Investigation of Their Some Transition Metal Complexes

Yazarlar:

Erdem Büyükaslan | Ahmed Hamdi Mirghani | Şaban Uysal

Yayıncı:

Necmettin Erbakan University

Ana Başlıklar:

Geçiş Metal Kimyası

Dergi:

Necmettin Erbakan Üniversitesi Fen ve Mühendislik Bilimleri Dergisi Vol.7 Issue 1, pp.126-140

Belge Tipi:

Makale

Yayın Tarihi:

4/2025

Belge Dili:

İngilizce

Document ID (Org No.):

2001338803

pISSN:

2667-7989

Anahtar kelimeler:

Özet:

 In this paper, two basic mid-products were obtained by reacting cyanuric chloride and hydroquinone or 1,4-phenylendiamine, respectively. EBA1 and EBA2 were obtained from the reaction of these compounds and 4-hydroxybenzaldehyde. Four target ligands encoded as EBL1-EBL4 were obtained by reacting these compounds with 4-aminobenzoic acid and 5-aminoisophthalic acid, respectively. These obtained ligands were characterized by FTIR, elemental analysis, 1H and 13C NMR and methods. The obtained target ligands were reacted with MSalenSaloph2O M Cr3 and Fe3 to obtain MSalenSaloph capped complexes. These complexes were characterized using elemental analysis, and FTIR. The magnetic properties of the complexes were investigated. The thermal endurance of the complexes was determined using the TGA technique. At the end of the study, 6 tetrapodal ligands and 16 tetrapodal complexes, which are thermally stable with paramagnetic properties, were synthesized and characterized.

 In this paper, two basic mid-products were obtained by reacting cyanuric chloride and hydroquinone or 1,4-phenylendiamine, respectively. EBA1 and EBA2 were obtained from the reaction of these compounds and 4-hydroxybenzaldehyde. Four target ligands encoded as EBL1-EBL4 were obtained by reacting these compounds with 4-aminobenzoic acid and 5-aminoisophthalic acid, respectively. These obtained ligands were characterized by FTIR, elemental analysis, 1H and 13C NMR and methods. The obtained target ligands were reacted with MSalenSaloph2O M Cr3 and Fe3 to obtain MSalenSaloph capped complexes. These complexes were characterized using elemental analysis, and FTIR. The magnetic properties of the complexes were investigated. The thermal endurance of the complexes was determined using the TGA technique. At the end of the study, 6 tetrapodal ligands and 16 tetrapodal complexes, which are thermally stable with paramagnetic properties, were synthesized and characterized.

 In this paper, two basic mid-products were obtained by reacting cyanuric chloride and hydroquinone or 1,4-phenylendiamine, respectively. EBA1 and EBA2 were obtained from the reaction of these compounds and 4-hydroxybenzaldehyde. Four target ligands encoded as EBL1-EBL4 were obtained by reacting these compounds with 4-aminobenzoic acid and 5-aminoisophthalic acid, respectively. These obtained ligands were characterized by FTIR, elemental analysis, 1H and 13C NMR and methods. The obtained target ligands were reacted with MSalenSaloph2O M Cr3 and Fe3 to obtain MSalenSaloph capped complexes. These complexes were characterized using elemental analysis, and FTIR. The magnetic properties of the complexes were investigated. The thermal endurance of the complexes was determined using the TGA technique. At the end of the study, 6 tetrapodal ligands and 16 tetrapodal complexes, which are thermally stable with paramagnetic properties, were synthesized and characterized.

 Bu çalışmada ilk olarak sırasıyla siyanürik klorür ve hidrokinon veya 1,4-fenilendiaminin reaksiyona sokulmasıyla iki bazik ara ürün elde edildi. Bu bileşiklerin 4-hidroksibenzaldehit ile reaksiyonundan EBA1 ve EBA2 elde edildi. Bu bileşiklerin sırasıyla 4-aminobenzoik asit ve 5-aminoizoftalik asit ile reaksiyona sokulmasıyla EBL1-EBL4 olarak kodlanan dört hedef ligand elde edildi. Elde edilen bu ligandlar, FTIR, elementel analiz, 1H ve 13C NMR yöntemleriyle karakterize edildi. Elde edilen hedef ligandların MSalenSaloph2O M Cr3 ve Fe3 ile reaksiyonu sonucu MSalenSaloph başlıklı kompleksler elde edildi. Bu kompleksler elementel analiz ve FTIR kullanılarak karakterize edildi. Komplekslerin manyetik özellikleri araştırıldı. Komplekslerin termal dayanıklılığı TGA tekniği kullanılarak belirlendi. Çalışmanın sonunda termal olarak kararlı ve paramanyetik özelliklere sahip 6 adet tetrapodal ligand ve 16 adet tetrapodal kompleks sentezlenmiş ve karakterize edilmiştir.

Makale detayları

Synthesis And Characterization of Multidentate Schiff Bases Containing s-Triazine: Investigation of Their Some Transition Metal Complexes

Yazarlar:

Erdem Büyükaslan | Ahmed Hamdi Mirghani | Şaban Uysal

Yayıncı:

Necmettin Erbakan University

Ana Başlıklar:

Geçiş Metal Kimyası

Dergi:

Necmettin Erbakan Üniversitesi Fen ve Mühendislik Bilimleri Dergisi Vol.7 Issue 1, pp.126-140

Belge Tipi:

Makale

Yayın Tarihi:

4/2025

Belge Dili:

İngilizce

Document ID (Org No.):

2001338803

pISSN:

2667-7989

Polydentate ligand

s-Triazine

Salen

SalophÇok dişli ligand

s-Triazin

Salen

Saloph

Sayı

Makale detayları

Yazarlar: Erdem Büyükaslan | Ahmed Hamdi Mirghani | Şaban Uysal

Yayıncı: Necmettin Erbakan University

Ana Başlıklar: Geçiş Metal Kimyası

Dergi: Necmettin Erbakan Üniversitesi Fen ve Mühendislik Bilimleri Dergisi Vol.7 Issue 1, pp.126-140

Belge Tipi: Makale

Yayın Tarihi: 4/2025

Belge Dili: İngilizce

Document ID (Org No.): 2001338803

pISSN: 2667-7989

Sayı

Yazarlar:

Erdem Büyükaslan | Ahmed Hamdi Mirghani | Şaban Uysal

Yayıncı:

Necmettin Erbakan University

Ana Başlıklar:

Geçiş Metal Kimyası

Dergi:

Necmettin Erbakan Üniversitesi Fen ve Mühendislik Bilimleri Dergisi Vol.7 Issue 1, pp.126-140

Belge Tipi:

Makale

Yayın Tarihi:

4/2025

Belge Dili:

İngilizce

Document ID (Org No.):

2001338803

pISSN:

2667-7989