Steric Effects on the Oxidation Potential of 1-aryl Thioglycosides

Mehmet A. OTURAN; Maurice MÉDEBIELLE

Makale detayları

Steric Effects on the Oxidation Potential of 1-aryl Thioglycosides

Yazarlar:

Mehmet A. OTURAN | Maurice MÉDEBIELLE

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2002 Vol.26 Issue 3, pp.317-322

Belge Tipi:

Makale

Yayın Tarihi:

2/2002

Belge Dili:

Türkçe

Document ID (Org No.):

2000729872

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

The electrochemical oxidation of several 1-arylthioglycosides has been   studied by cyclic voltammetry in acetonitrile. We found that the   oxidation potential of the a  anomer always occurs at a less positive   oxidation potential than of the b  anomer. The difference in the   oxidation potential depends on the substituent attached on the C-3 of the   sugar moiety and is greatly influenced by the stability of the radical   cation obtained after the first electron transfer.

 

The electrochemical oxidation of several 1-arylthioglycosides has been   studied by cyclic voltammetry in acetonitrile. We found that the   oxidation potential of the a  anomer always occurs at a less positive   oxidation potential than of the b  anomer. The difference in the   oxidation potential depends on the substituent attached on the C-3 of the   sugar moiety and is greatly influenced by the stability of the radical   cation obtained after the first electron transfer.

Makale detayları

Steric Effects on the Oxidation Potential of 1-aryl Thioglycosides

Yazarlar: Mehmet A. OTURAN | Maurice MÉDEBIELLE

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2002 Vol.26 Issue 3, pp.317-322

Belge Tipi: Makale

Yayın Tarihi: 2/2002

Belge Dili: Türkçe

Document ID (Org No.): 2000729872

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Mehmet A. OTURAN | Maurice MÉDEBIELLE

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2002 Vol.26 Issue 3, pp.317-322

Belge Tipi:

Makale

Yayın Tarihi:

2/2002

Belge Dili:

Türkçe

Document ID (Org No.):

2000729872

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527