Asymmetric Henry reaction catalyzed by Cu(I)-based chiral amino alcohol complex

Tianhua SHEN; Quan QIN; Hang NI; Ting XIA; Xiaocong ZHOU; Funa CUI; Junqi LI; Deqiang RAN; Qingbao SONG

Makale detayları

Asymmetric Henry reaction catalyzed by Cu(I)-based chiral amino alcohol complex

Yazarlar:

Tianhua SHEN | Quan QIN | Hang NI | Ting XIA | Xiaocong ZHOU | Funa CUI | Junqi LI | Deqiang RAN | Qingbao SONG

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2013 Vol.37 Issue 6, pp.966-977

Belge Tipi:

Makale

Yayın Tarihi:

5/2013

Belge Dili:

Türkçe

Document ID (Org No.):

2000727302

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

The Cu(I)-based complex prepared from  (S)-2-(furan-2-yl-methylamino)-2-phenylethanol (5c) and CuCl was  used as catalyst in enantioselective Henry reactions of arylaldehydes and  nitromethane, which gave 89% ee and 95% yield at ambient temperature.  The proposed catalytic cycle of an asymmetric Henry reaction was suggested.

 

The Cu(I)-based complex prepared from  (S)-2-(furan-2-yl-methylamino)-2-phenylethanol (5c) and CuCl was  used as catalyst in enantioselective Henry reactions of arylaldehydes and  nitromethane, which gave 89% ee and 95% yield at ambient temperature.  The proposed catalytic cycle of an asymmetric Henry reaction was suggested.

Makale detayları

Asymmetric Henry reaction catalyzed by Cu(I)-based chiral amino alcohol complex

Yazarlar: Tianhua SHEN | Quan QIN | Hang NI | Ting XIA | Xiaocong ZHOU | Funa CUI | Junqi LI | Deqiang RAN | Qingbao SONG

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2013 Vol.37 Issue 6, pp.966-977

Belge Tipi: Makale

Yayın Tarihi: 5/2013

Belge Dili: Türkçe

Document ID (Org No.): 2000727302

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Tianhua SHEN | Quan QIN | Hang NI | Ting XIA | Xiaocong ZHOU | Funa CUI | Junqi LI | Deqiang RAN | Qingbao SONG

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2013 Vol.37 Issue 6, pp.966-977

Belge Tipi:

Makale

Yayın Tarihi:

5/2013

Belge Dili:

Türkçe

Document ID (Org No.):

2000727302

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527