A novel soluble phthalocyanine capable of binding four boronic esters

Şennur ÖZÇELİK; Gülnur KESER KARAOĞLAN; Gülşah GÜMRÜKÇÜ

Makale detayları

A novel soluble phthalocyanine capable of binding four boronic esters

Yazarlar:

Şennur ÖZÇELİK | Gülnur KESER KARAOĞLAN | Gülşah GÜMRÜKÇÜ

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2012 Vol.36 Issue 6, pp.899-906

Belge Tipi:

Makale

Yayın Tarihi:

5/2012

Belge Dili:

Türkçe

Document ID (Org No.):

2000727534

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

A novel Zn phthalocyanine bearing 4 salicylideniminophenyloxy  substituents on peripheral positions was synthesized from the reaction  of 4-aminophenoxy substituted phthalocyanine and salicylaldehyde.  The  condensation reaction of salicylidene Schiff base groups and  benzeneboronic acid produced a new phthalocyanine carrying  benzeneboronic acid ester derivatives as substituents.  Ethoxy groups  were bound to boronic acid as a second ligand.  The presence of B-N  bond interactions enhanced the stability of this boronated  phthalocyanine derivative, which exhibited sufficient air stability  during the purification and characterization processes.  The novel  compounds were characterized by using elemental analysis, IR, 1H-NMR,  11B-NMR, 13C-NMR, UV-Vis and MALDI-TOF MS spectral data.

 

A novel Zn phthalocyanine bearing 4 salicylideniminophenyloxy  substituents on peripheral positions was synthesized from the reaction  of 4-aminophenoxy substituted phthalocyanine and salicylaldehyde.  The  condensation reaction of salicylidene Schiff base groups and  benzeneboronic acid produced a new phthalocyanine carrying  benzeneboronic acid ester derivatives as substituents.  Ethoxy groups  were bound to boronic acid as a second ligand.  The presence of B-N  bond interactions enhanced the stability of this boronated  phthalocyanine derivative, which exhibited sufficient air stability  during the purification and characterization processes.  The novel  compounds were characterized by using elemental analysis, IR, 1H-NMR,  11B-NMR, 13C-NMR, UV-Vis and MALDI-TOF MS spectral data.

Makale detayları

A novel soluble phthalocyanine capable of binding four boronic esters

Yazarlar: Şennur ÖZÇELİK | Gülnur KESER KARAOĞLAN | Gülşah GÜMRÜKÇÜ

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2012 Vol.36 Issue 6, pp.899-906

Belge Tipi: Makale

Yayın Tarihi: 5/2012

Belge Dili: Türkçe

Document ID (Org No.): 2000727534

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Şennur ÖZÇELİK | Gülnur KESER KARAOĞLAN | Gülşah GÜMRÜKÇÜ

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2012 Vol.36 Issue 6, pp.899-906

Belge Tipi:

Makale

Yayın Tarihi:

5/2012

Belge Dili:

Türkçe

Document ID (Org No.):

2000727534

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527