Methyltriphenylphosphonium Halochromates, [Me(Ph)3P][CrO3X] (MTriPPXC) (X= F, Cl, Br): the Three New, Mild and Stable Oxidants for Organic Substrates

Shahriare GHAMMAMY; Kheyrollah MEHRANI; Saeid MALEKI; Zahra JAVANSHIR

Makale detayları

Methyltriphenylphosphonium Halochromates, [Me(Ph)3P][CrO3X] (MTriPPXC) (X= F, Cl, Br): the Three New, Mild and Stable Oxidants for Organic Substrates

Yazarlar:

Shahriare GHAMMAMY | Kheyrollah MEHRANI | Saeid MALEKI | Zahra JAVANSHIR

Yayıncı:

Gazi University

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Gazi University Journal of Science 2008 Vol.21 Issue 2, pp.33-36

Belge Tipi:

Makale

Yayın Tarihi:

3/2010

Belge Dili:

İngilizce

Document ID (Org No.):

2000430042

eISSN:

2147-1762

Özet:

 

   

Methyltriphenylphosphonium Halochromates (MTriPPXC) were prepared and used for oxidation of alcohols under mild conditions. These new compounds are more efficient and have certain advantages over similar oxidizing agents in terms of the amount of oxidants, short reaction times, and high yields. Methyltriphenylphosphonium Halochromates, Me(Ph)3PCrO3X (MTriPPXC) (X= F, Cl, Br) are easily synthesized by the reaction of Methyltriphenylphosphonium with an aqueous solution of CrO3 and HX in a 1:1:2 mole ratio. The reactions were carried out in solution, under mild and acid-free conditions.

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Makale detayları

Methyltriphenylphosphonium Halochromates, [Me(Ph)3P][CrO3X] (MTriPPXC) (X= F, Cl, Br): the Three New, Mild and Stable Oxidants for Organic Substrates

Yazarlar: Shahriare GHAMMAMY | Kheyrollah MEHRANI | Saeid MALEKI | Zahra JAVANSHIR

Yayıncı: Gazi University

Ana Başlıklar: Uygulamalı fizik

Dergi: Gazi University Journal of Science 2008 Vol.21 Issue 2, pp.33-36

Belge Tipi: Makale

Yayın Tarihi: 3/2010

Belge Dili: İngilizce

Document ID (Org No.): 2000430042

eISSN: 2147-1762

Sayı

Yazarlar:

Shahriare GHAMMAMY | Kheyrollah MEHRANI | Saeid MALEKI | Zahra JAVANSHIR

Yayıncı:

Gazi University

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Gazi University Journal of Science 2008 Vol.21 Issue 2, pp.33-36

Belge Tipi:

Makale

Yayın Tarihi:

3/2010

Belge Dili:

İngilizce

Document ID (Org No.):

2000430042

eISSN:

2147-1762