Synthesis, properties, and electrochemistry of a photochromic compound based on dithienylethene and ProDOT

Melek PAMUK ALGI; Atilla CİHANER; Fatih ALGI

doi:https://doi.org/10.3906/kim-1406-49

Makale detayları

Synthesis, properties, and electrochemistry of a photochromic compound based on dithienylethene and ProDOT

Yazarlar:

Melek PAMUK ALGI | Atilla CİHANER | Fatih ALGI

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2015 Vol.39 Issue 1, pp.139-148

Belge Tipi:

Makale

Yayın Tarihi:

3/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000726982

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

DOI:

https://doi.org/10.3906/kim-1406-49

Özet:

 

The synthesis, photochromic features, and electrochemistry of a novel  material based on dithienylethene (DTE) and  3,3-didecyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine (didecyl-ProDOT)  units are described. It is noteworthy that  1,2-bis(5-(3,3-didecyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepin-6-yl)-2-methylthiophen-3-yl)cyclopent-1-ene  can be efficiently switched between open and closed states by light in both  solution and in the solid poly(methyl metacrylate) (PMMA) matrix. It is also  found that the emission of this novel compound can be switched on and off  upon irradiation.

 

The synthesis, photochromic features, and electrochemistry of a novel  material based on dithienylethene (DTE) and  3,3-didecyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepine (didecyl-ProDOT)  units are described. It is noteworthy that  1,2-bis(5-(3,3-didecyl-3,4-dihydro-2H-thieno[3,4-b][1,4]dioxepin-6-yl)-2-methylthiophen-3-yl)cyclopent-1-ene  can be efficiently switched between open and closed states by light in both  solution and in the solid poly(methyl metacrylate) (PMMA) matrix. It is also  found that the emission of this novel compound can be switched on and off  upon irradiation.

Makale detayları

Synthesis, properties, and electrochemistry of a photochromic compound based on dithienylethene and ProDOT

Yazarlar: Melek PAMUK ALGI | Atilla CİHANER | Fatih ALGI

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2015 Vol.39 Issue 1, pp.139-148

Belge Tipi: Makale

Yayın Tarihi: 3/2015

Belge Dili: İngilizce

Document ID (Org No.): 2000726982

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

DOI: https://doi.org/10.3906/kim-1406-49

Sayı

Yazarlar:

Melek PAMUK ALGI | Atilla CİHANER | Fatih ALGI

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2015 Vol.39 Issue 1, pp.139-148

Belge Tipi:

Makale

Yayın Tarihi:

3/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000726982

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

DOI:

https://doi.org/10.3906/kim-1406-49