Synthesis and Characterization of Zn(II) Complexes of 2-Amino-6-substituepyridine Derivatives and 5-Sulfosalicylic Acid

Halil İlkimen; Cengiz Yenikaya; Zeynep Alkan Alkaya

Makale detayları

Synthesis and Characterization of Zn(II) Complexes of 2-Amino-6-substituepyridine Derivatives and 5-Sulfosalicylic Acid

Yazarlar:

Halil İlkimen | Cengiz Yenikaya | Zeynep Alkan Alkaya

Yayıncı:

Selcuk University

Ana Başlıklar:

Transition Metal Chemistry

Dergi:

Selcuk University Journal of Science Faculty Vol.50 Issue 2, pp.43-48

Belge Tipi:

Makale

Yayın Tarihi:

1/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001327757

pISSN:

2458-9411

Anahtar kelimeler:

Özet:

 This study, four new ZnII complexes HX2ZnHssal2H2O2, H3ssal: 5-sulfosalicylic acid, X  2-amino-6-methylpyridine 1 for 5, 2-amino-3-ethyl-6-methylpyridine 2 for 6, 2-amino-3-nitro-6-methylpyridine 3 for 7, and ZnHssalX2H2O2, X  2-amino-3-nitro-6-chloropyridine 4 for 8 were synthesized. The structures of ZnII complexes 5-8 were characterized by elemental analysis, AAS, FT-IR, molar conductivity and magnetic susceptibility analyses. The results of IR and conductivity analyses, it was observed that 5-7 metal complexes were ionic, while 8 metal complexes were non-ionic. AAS and elemental analysis tests also support these results. In magnetic susceptibility studies, it was observed that ZnII d10 metal complexes did not carry unpaired electrons as expected. The results of the spectroscopic analysis of complexes 5-8 have an octahedral structure.

 This study, four new ZnII complexes HX2ZnHssal2H2O2, H3ssal: 5-sulfosalicylic acid, X  2-amino-6-methylpyridine 1 for 5, 2-amino-3-ethyl-6-methylpyridine 2 for 6, 2-amino-3-nitro-6-methylpyridine 3 for 7, and ZnHssalX2H2O2, X  2-amino-3-nitro-6-chloropyridine 4 for 8 were synthesized. The structures of ZnII complexes 5-8 were characterized by elemental analysis, AAS, FT-IR, molar conductivity and magnetic susceptibility analyses. The results of IR and conductivity analyses, it was observed that 5-7 metal complexes were ionic, while 8 metal complexes were non-ionic. AAS and elemental analysis tests also support these results. In magnetic susceptibility studies, it was observed that ZnII d10 metal complexes did not carry unpaired electrons as expected. The results of the spectroscopic analysis of complexes 5-8 have an octahedral structure.

 This study, four new ZnII complexes HX2ZnHssal2H2O2, H3ssal: 5-sulfosalicylic acid, X  2-amino-6-methylpyridine 1 for 5, 2-amino-3-ethyl-6-methylpyridine 2 for 6, 2-amino-3-nitro-6-methylpyridine 3 for 7, and ZnHssalX2H2O2, X  2-amino-3-nitro-6-chloropyridine 4 for 8 were synthesized. The structures of ZnII complexes 5-8 were characterized by elemental analysis, AAS, FT-IR, molar conductivity and magnetic susceptibility analyses. The results of IR and conductivity analyses, it was observed that 5-7 metal complexes were ionic, while 8 metal complexes were non-ionic. AAS and elemental analysis tests also support these results. In magnetic susceptibility studies, it was observed that ZnII d10 metal complexes did not carry unpaired electrons as expected. The results of the spectroscopic analysis of complexes 5-8 have an octahedral structure.

 Bu çalışmada, dört yeni ZnII kompleksleri HX2ZnHssal2H2O2, H3ssal: 5-sülfosalisilik asit, X  5 için 2-amino-6-metilpiridin 1, 6 için 2-amino-3-etil-6-metilpiridin 2 ve 7 için 2-amino-3-nitro-6-metilpiridin 3 ve ZnHssalX2H2O2 X  8 için 2-amino-3-nitro-6-kloropiridin 4 elde edildi. ZnII komplekslerinin yapıları element analizi, AAS, FT-IR, molar iletkenlik ve manyetik duyarlılık analizleri ile karakterize edildi. IR ve iletkenlik analizleri sonucunda 5-7 metal komplekslerinin iyonik olduğu ve 8 metal kompleksinin ise iyonik olmadığı gözlenmiştir. Bu sonuçları AAS ve elementel analiz testleri de desteklemektedir. Manyetik duyarlılık çalışmalarında ZnII d10 metal komplekslerinin beklendiği gibi eşleşmemiş elektron taşımadıkları gözlenmiştir. Yapılan spektroskopik analiz sonuçlarında tüm komplekslerin 5-8 oktahedral yapıya sahip oldukları önerilmiştir.

Makale detayları

Synthesis and Characterization of Zn(II) Complexes of 2-Amino-6-substituepyridine Derivatives and 5-Sulfosalicylic Acid

Yazarlar:

Halil İlkimen | Cengiz Yenikaya | Zeynep Alkan Alkaya

Yayıncı:

Selcuk University

Ana Başlıklar:

Transition Metal Chemistry

Dergi:

Selcuk University Journal of Science Faculty Vol.50 Issue 2, pp.43-48

Belge Tipi:

Makale

Yayın Tarihi:

1/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001327757

pISSN:

2458-9411

5-Sulfosalicylic acid

2-Aminopyridine

Zn(II) complex

Octahedral structure5-Sülfosalisilik asit

2-Aminopiridin

Zn(II) kompleksi

Oktahedral yapı

Sayı

Makale detayları

Yazarlar: Halil İlkimen | Cengiz Yenikaya | Zeynep Alkan Alkaya

Yayıncı: Selcuk University

Ana Başlıklar: Transition Metal Chemistry

Dergi: Selcuk University Journal of Science Faculty Vol.50 Issue 2, pp.43-48

Belge Tipi: Makale

Yayın Tarihi: 1/2024

Belge Dili: Türkçe

Document ID (Org No.): 2001327757

pISSN: 2458-9411

Sayı

Yazarlar:

Halil İlkimen | Cengiz Yenikaya | Zeynep Alkan Alkaya

Yayıncı:

Selcuk University

Ana Başlıklar:

Transition Metal Chemistry

Dergi:

Selcuk University Journal of Science Faculty Vol.50 Issue 2, pp.43-48

Belge Tipi:

Makale

Yayın Tarihi:

1/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001327757

pISSN:

2458-9411