The Crystal Structure of 2-Nitro-N-(4-nitrophenyl)benzamide

Aamer SAEED; Shahid HUSSAIN and Ulrich FLÖRKE; Shahid HUSSAIN; Ulrich FLÖRKE

Makale detayları

The Crystal Structure of 2-Nitro-N-(4-nitrophenyl)benzamide

Yazarlar:

Aamer SAEED | Shahid HUSSAIN and Ulrich FLÖRKE | Shahid HUSSAIN | Ulrich FLÖRKE

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2008 Vol.32 Issue 4, pp.481-486

Belge Tipi:

Makale

Yayın Tarihi:

3/2008

Belge Dili:

Türkçe

Document ID (Org No.):

2000728478

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

2-Nitro-N-(4-nitrophenyl)benzamide was synthesized and  characterized by spectroscopy and elemental analysis.  The crystal  structure was determined from single-crystal X-ray diffraction data.  It crystallizes in the orthorhombic space group, P 212121, with  unit cell dimensions a = 8.9443(10) Å, b = 9.7147(11) Å, and c =  13.8016(16) Å.  The dihedral angle between the 2 aromatic rings is  82.32(4)\circ.  The N2 and N3 nitro groups are oriented with  respect to their attached phenyl rings at dihedral angles of  1.97(3)\circ and 15.73(3)\circ, respectively.  The  intramolecular C-H{\ldots}O hydrogen bond results in the formation of  a non-planar 6-membered ring.  In the crystal structure,  intermolecular N-H...O hydrogen bonds seem to be effective in the  stabilization of the structure, resulting in the formation of a  3-dimensional network.

 

2-Nitro-N-(4-nitrophenyl)benzamide was synthesized and  characterized by spectroscopy and elemental analysis.  The crystal  structure was determined from single-crystal X-ray diffraction data.  It crystallizes in the orthorhombic space group, P 212121, with  unit cell dimensions a = 8.9443(10) Å, b = 9.7147(11) Å, and c =  13.8016(16) Å.  The dihedral angle between the 2 aromatic rings is  82.32(4)\circ.  The N2 and N3 nitro groups are oriented with  respect to their attached phenyl rings at dihedral angles of  1.97(3)\circ and 15.73(3)\circ, respectively.  The  intramolecular C-H{\ldots}O hydrogen bond results in the formation of  a non-planar 6-membered ring.  In the crystal structure,  intermolecular N-H...O hydrogen bonds seem to be effective in the  stabilization of the structure, resulting in the formation of a  3-dimensional network.

Makale detayları

The Crystal Structure of 2-Nitro-N-(4-nitrophenyl)benzamide

Yazarlar: Aamer SAEED | Shahid HUSSAIN and Ulrich FLÖRKE | Shahid HUSSAIN | Ulrich FLÖRKE

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2008 Vol.32 Issue 4, pp.481-486

Belge Tipi: Makale

Yayın Tarihi: 3/2008

Belge Dili: Türkçe

Document ID (Org No.): 2000728478

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Aamer SAEED | Shahid HUSSAIN and Ulrich FLÖRKE | Shahid HUSSAIN | Ulrich FLÖRKE

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2008 Vol.32 Issue 4, pp.481-486

Belge Tipi:

Makale

Yayın Tarihi:

3/2008

Belge Dili:

Türkçe

Document ID (Org No.):

2000728478

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527