Synthesis, X-ray Structure, and Bioassay of Newly Synthesized Trimethyltin(IV) 2,3-Methylenedioxy Benzoate

Mukhtiar HUSSAIN; Muhammad HANIF; Saqib ALI

Makale detayları

Synthesis, X-ray Structure, and Bioassay of Newly Synthesized Trimethyltin(IV) 2,3-Methylenedioxy Benzoate

Yazarlar:

Mukhtiar HUSSAIN | Muhammad HANIF | Saqib ALI

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2008 Vol.32 Issue 1, pp.25-33

Belge Tipi:

Makale

Yayın Tarihi:

12/2007

Belge Dili:

İngilizce

Document ID (Org No.):

2000728556

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

Trimethyltin(IV) complex containing the carboxylate ligand  2,3-methylenedioxybenzoic acid (HL) have been synthesized and  characterized in solution state by multinuclear NMR (1H, 13C and  119Sn) using the noncoordinating solvent and also in solid sate by  FTIR, mass spectrometry, and X-ray crystallography.  Spectroscopic  data have shown that methylenedioxy moiety has not coordinated with  tin atom; instead, the coordination site is a -COO group, which is  proved by spectral and XRD data.  The solid state structure shows the  trigonal bipyramidal geometry with a space group P21/c.  This  compound was tested for its in vitro antitumor activity.

 

Trimethyltin(IV) complex containing the carboxylate ligand  2,3-methylenedioxybenzoic acid (HL) have been synthesized and  characterized in solution state by multinuclear NMR (1H, 13C and  119Sn) using the noncoordinating solvent and also in solid sate by  FTIR, mass spectrometry, and X-ray crystallography.  Spectroscopic  data have shown that methylenedioxy moiety has not coordinated with  tin atom; instead, the coordination site is a -COO group, which is  proved by spectral and XRD data.  The solid state structure shows the  trigonal bipyramidal geometry with a space group P21/c.  This  compound was tested for its in vitro antitumor activity.

Makale detayları

Synthesis, X-ray Structure, and Bioassay of Newly Synthesized Trimethyltin(IV) 2,3-Methylenedioxy Benzoate

Yazarlar: Mukhtiar HUSSAIN | Muhammad HANIF | Saqib ALI

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2008 Vol.32 Issue 1, pp.25-33

Belge Tipi: Makale

Yayın Tarihi: 12/2007

Belge Dili: İngilizce

Document ID (Org No.): 2000728556

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Mukhtiar HUSSAIN | Muhammad HANIF | Saqib ALI

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2008 Vol.32 Issue 1, pp.25-33

Belge Tipi:

Makale

Yayın Tarihi:

12/2007

Belge Dili:

İngilizce

Document ID (Org No.):

2000728556

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527