Kinetics of silver(I)-catalyzed oxidation of allyl alcohol by peroxodiphosphate in  acetate buffers

Priyamvada SHARMA; Riya SAILANI; Deepmala PAREEK; Chandra Lata KHANDELWAL

Makale detayları

Kinetics of silver(I)-catalyzed oxidation of allyl alcohol by peroxodiphosphate in acetate buffers

Yazarlar:

Priyamvada SHARMA | Riya SAILANI | Deepmala PAREEK | Chandra Lata KHANDELWAL

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2018 Vol.42 Issue 1, pp.158-169

Belge Tipi:

Makale

Yayın Tarihi:

1/2018

Belge Dili:

Türkçe

Document ID (Org No.):

2000726259

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

The kinetics and mechanism of silver(I)-catalyzed oxidation of allyl alcohol with peroxodiphosphate in acetate  buffers have been studied. The rate is independent of allyl alcohol concentration. The effect of other reaction parameters  such as hydrogen and acetate ions has also been studied. The rate law accounting for all experimental observations  corresponds to the proposed mechanism. The energy and entropy of activation have also been evaluated by employing  Eyring plots.

Makale detayları

Kinetics of silver(I)-catalyzed oxidation of allyl alcohol by peroxodiphosphate in acetate buffers

Yazarlar: Priyamvada SHARMA | Riya SAILANI | Deepmala PAREEK | Chandra Lata KHANDELWAL

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2018 Vol.42 Issue 1, pp.158-169

Belge Tipi: Makale

Yayın Tarihi: 1/2018

Belge Dili: Türkçe

Document ID (Org No.): 2000726259

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Priyamvada SHARMA | Riya SAILANI | Deepmala PAREEK | Chandra Lata KHANDELWAL

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2018 Vol.42 Issue 1, pp.158-169

Belge Tipi:

Makale

Yayın Tarihi:

1/2018

Belge Dili:

Türkçe

Document ID (Org No.):

2000726259

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527