THEORETICAL EXPLANATION FOR CATALYTIC HYDROSILYLATION OF SOME ORGANIC MOLECULES MEDIATED BY A PHOSPHORUS DICATION COMPOUND

Cem Burak YILDIZ

doi:https://doi.org/10.20290/estubtdb.898776

Makale detayları

THEORETICAL EXPLANATION FOR CATALYTIC HYDROSILYLATION OF SOME ORGANIC MOLECULES MEDIATED BY A PHOSPHORUS DICATION COMPOUND

Yazarlar:

Cem Burak YILDIZ

Yayıncı:

Eskisehir Technical University

Ana Başlıklar:

Astronomi ve ilgili bilimler

Dergi:

Eskişehir Teknik Üniversitesi Bilim ve Teknoloji Dergisi B - Teorik Bilimler 2021 Vol.9 Issue 2, pp.30-36

Belge Tipi:

Makale

Yayın Tarihi:

8/2021

Belge Dili:

İngilizce

Document ID (Org No.):

2000417572

pISSN:

2667-419X

DOI:

https://doi.org/10.20290/estubtdb.898776

Özet:

 

Catalysis reactions under metal-free and ambient conditions have received great interest in terms of economic and environmental issues. Especially, the applications of Lewis acids for the processes are having special interest due to their unique roles in a huge number of organic reactions. In this sense, a recent compound PIII dication has played an important role in the catalytic hydrosilylation of carbonyls and olefins. Herein theoretical calculations were carried out to elucidate the mechanisms of the experimentally reported and unknown reactions. The proposed mechanisms show that the reactions of a-d can occur spontaneously, whereas the formation of pyridine has endergonic nature.

 

Catalysis reactions under metal-free and ambient conditions have received great interest in terms of economic and environmental issues. Especially, the applications of Lewis acids for the processes are having special interest due to their unique roles in a huge number of organic reactions. In this sense, a recent compound PIII dication has played an important role in the catalytic hydrosilylation of carbonyls and olefins. Herein theoretical calculations were carried out to elucidate the mechanisms of the experimentally reported and unknown reactions. The proposed mechanisms show that the reactions of a-d can occur spontaneously, whereas the formation of pyridine has endergonic nature.

Makale detayları

THEORETICAL EXPLANATION FOR CATALYTIC HYDROSILYLATION OF SOME ORGANIC MOLECULES MEDIATED BY A PHOSPHORUS DICATION COMPOUND

Yazarlar: Cem Burak YILDIZ

Yayıncı: Eskisehir Technical University

Ana Başlıklar: Astronomi ve ilgili bilimler

Dergi: Eskişehir Teknik Üniversitesi Bilim ve Teknoloji Dergisi B - Teorik Bilimler 2021 Vol.9 Issue 2, pp.30-36

Belge Tipi: Makale

Yayın Tarihi: 8/2021

Belge Dili: İngilizce

Document ID (Org No.): 2000417572

pISSN: 2667-419X

DOI: https://doi.org/10.20290/estubtdb.898776

Sayı

Yazarlar:

Cem Burak YILDIZ

Yayıncı:

Eskisehir Technical University

Ana Başlıklar:

Astronomi ve ilgili bilimler

Dergi:

Eskişehir Teknik Üniversitesi Bilim ve Teknoloji Dergisi B - Teorik Bilimler 2021 Vol.9 Issue 2, pp.30-36

Belge Tipi:

Makale

Yayın Tarihi:

8/2021

Belge Dili:

İngilizce

Document ID (Org No.):

2000417572

pISSN:

2667-419X

DOI:

https://doi.org/10.20290/estubtdb.898776