Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterization

Omer YURDAKUL; Dursun Ali KOSE

doi:https://doi.org/10.17350/HJSE19030000008

Makale detayları

Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterization

Yazarlar:

Omer YURDAKUL | Dursun Ali KOSE

Yayıncı:

Hitit University

Dergi:

Hittite Journal of Science and Engineering 2014 Vol.1 Issue 1, pp.51-57

Belge Tipi:

Makale

Yayın Tarihi:

12/2014

Belge Dili:

İngilizce

Document ID (Org No.):

2000451925

Sıklık:

Üç Aylık

eISSN:

2148-4171

DOI:

https://doi.org/10.17350/HJSE19030000008

Özet:

 

In the scope of this study, acesulfame  ace, acs -nicotinamide  na  mixed ligand complexes of Mg II , Ca II , Sr II  and Ba II  were synthesized for the first time. Possible formulas for complexes were determined as [Mg H2O 4 na 2] acs 2, [Ca H2O 6 na 2] acs 2, [Sr H2O 7 na 2] acs 2, [Ba H2O 7 na 2] acs 2 . It was observed that acesulfame ligands within structure were located two moles each at outer surface of coordination sphere acting as counter-ion allowing the charge balance of structure. The solubility of compounds gaining ionic character in this way was determined as quite well as compared to complex structures. Characterizations of complexes synthesized were performed via melting point analysis, elemental analysis, mass spectroscopy and FT-IR spectroscopy methods. Thermal properties of complexes obtained were determined with tandem TG-DTG and DTA techniques. It was found that the coordination spheres of metal cations within compounds obtained in this study were filled with nicotinamide and aqua ligands.

Makale detayları

Mixed ligand complexes of acesulfame/nicotinamide with earth alkaline metal cations MgII, CaII, BaII and SrII: synthesis and characterization

Yazarlar: Omer YURDAKUL | Dursun Ali KOSE

Yayıncı: Hitit University

Dergi: Hittite Journal of Science and Engineering 2014 Vol.1 Issue 1, pp.51-57

Belge Tipi: Makale

Yayın Tarihi: 12/2014

Belge Dili: İngilizce

Document ID (Org No.): 2000451925

Sıklık: Üç Aylık

eISSN: 2148-4171

DOI: https://doi.org/10.17350/HJSE19030000008

Sayı

Yazarlar:

Omer YURDAKUL | Dursun Ali KOSE

Yayıncı:

Hitit University

Dergi:

Hittite Journal of Science and Engineering 2014 Vol.1 Issue 1, pp.51-57

Belge Tipi:

Makale

Yayın Tarihi:

12/2014

Belge Dili:

İngilizce

Document ID (Org No.):

2000451925

Sıklık:

Üç Aylık

eISSN:

2148-4171

DOI:

https://doi.org/10.17350/HJSE19030000008