Suzuki-Miyaura Coupling Polymerization: Synthesis, Characterization and Optical Properties

Adnan Çetin

Makale detayları

Suzuki-Miyaura Coupling Polymerization: Synthesis, Characterization and Optical Properties

Yazarlar:

Adnan Çetin

Yayıncı:

Igdir University

Ana Başlıklar:

Kimya Mühendisliği

Dergi:

Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.13 Issue 1, pp.494-503

Belge Tipi:

Makale

Yayın Tarihi:

1/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001284065

pISSN:

2536-4618

Anahtar kelimeler:

Özet:

 The new thiazole-based polymer was synthesized by the Suzuki-Miyaura crossing-coupling reaction of 5-bromo-N-3-bromophenylthiazol-2-amine and 9,9-dioctyl-9H-fluorene-2,7-diboronic acid bispinacol ester. The synthesized monomer and polyN,N1,3-phenylenebisthiazol-2-amine-co9,9dioctylfluorene PolyTm were characterized by the Elemental analysis, Fourier Transform Infrared spectroscopy, Nuclear Magnetic Resonance spectroscopy, Thermogravimetric analysis and Gel Permission chromatography. Furthermore, the optical properties of the PolyTm were studied at three concentrations of 0.625, 1.25 and 2.5 mM in solution. The absorption band edge values of PolyTm decreased with the increasing concentration of the solutions. When the concentration of the PolyTm solution was increased, transmittance values of the PolyTm were increased, and its molar extinction coefficient was resulted in higher absorbance values. Synthesized PolyTm could provide a novel concept for the design of transistors and photovoltaics.

 The new thiazole-based polymer was synthesized by the Suzuki-Miyaura crossing-coupling reaction of 5-bromo-N-3-bromophenylthiazol-2-amine and 9,9-dioctyl-9H-fluorene-2,7-diboronic acid bispinacol ester. The synthesized monomer and polyN,N1,3-phenylenebisthiazol-2-amine-co9,9dioctylfluorene PolyTm were characterized by the Elemental analysis, Fourier Transform Infrared spectroscopy, Nuclear Magnetic Resonance spectroscopy, Thermogravimetric analysis and Gel Permission chromatography. Furthermore, the optical properties of the PolyTm were studied at three concentrations of 0.625, 1.25 and 2.5 mM in solution. The absorption band edge values of PolyTm decreased with the increasing concentration of the solutions. When the concentration of the PolyTm solution was increased, transmittance values of the PolyTm were increased, and its molar extinction coefficient was resulted in higher absorbance values. Synthesized PolyTm could provide a novel concept for the design of transistors and photovoltaics.

 The new thiazole-based polymer was synthesized by the Suzuki-Miyaura crossing-coupling reaction of 5-bromo-N-3-bromophenylthiazol-2-amine and 9,9-dioctyl-9H-fluorene-2,7-diboronic acid bispinacol ester. The synthesized monomer and polyN,N1,3-phenylenebisthiazol-2-amine-co9,9dioctylfluorene PolyTm were characterized by the Elemental analysis, Fourier Transform Infrared spectroscopy, Nuclear Magnetic Resonance spectroscopy, Thermogravimetric analysis and Gel Permission chromatography. Furthermore, the optical properties of the PolyTm were studied at three concentrations of 0.625, 1.25 and 2.5 mM in solution. The absorption band edge values of PolyTm decreased with the increasing concentration of the solutions. When the concentration of the PolyTm solution was increased, transmittance values of the PolyTm were increased, and its molar extinction coefficient was resulted in higher absorbance values. Synthesized PolyTm could provide a novel concept for the design of transistors and photovoltaics.

 The new thiazole-based polymer was synthesized by the Suzuki-Miyaura crossing-coupling reaction of 5-bromo-N-3-bromophenylthiazol-2-amine and 9,9-dioctyl-9H-fluorene-2,7-diboronic acid bispinacol ester. The synthesized monomer and polyN,N1,3-phenylenebisthiazol-2-amine-co9,9dioctylfluorene PolyTm were characterized by the Elemental analysis, Fourier Transform Infrared spectroscopy, Nuclear Magnetic Resonance spectroscopy, Thermogravimetric analysis and Gel Permission chromatography. Furthermore, the optical properties of the PolyTm were studied at three concentrations of 0.625, 1.25 and 2.5 mM in solution. The absorption band edge values of PolyTm decreased with the increasing concentration of the solutions. When the concentration of the PolyTm solution was increased, transmittance values of the PolyTm were increased, and its molar extinction coefficient was resulted in higher absorbance values. Synthesized PolyTm could provide a novel concept for the design of transistors and photovoltaics.

Makale detayları

Suzuki-Miyaura Coupling Polymerization: Synthesis, Characterization and Optical Properties

Yazarlar:

Adnan Çetin

Yayıncı:

Igdir University

Ana Başlıklar:

Kimya Mühendisliği

Dergi:

Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.13 Issue 1, pp.494-503

Belge Tipi:

Makale

Yayın Tarihi:

1/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001284065

pISSN:

2536-4618

Band edge

fluorene

optical constant

palladium catalyst

thiazole

Sayı

Makale detayları

Suzuki-Miyaura Coupling Polymerization: Synthesis, Characterization and Optical Properties

Yazarlar: Adnan Çetin

Yayıncı: Igdir University

Ana Başlıklar: Kimya Mühendisliği

Dergi: Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.13 Issue 1, pp.494-503

Belge Tipi: Makale

Yayın Tarihi: 1/2023

Belge Dili: İngilizce

Document ID (Org No.): 2001284065

pISSN: 2536-4618

Band edge

fluorene

optical constant

palladium catalyst

thiazole

Sayı

Yazarlar:

Adnan Çetin

Yayıncı:

Igdir University

Ana Başlıklar:

Kimya Mühendisliği

Dergi:

Iğdır Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.13 Issue 1, pp.494-503

Belge Tipi:

Makale

Yayın Tarihi:

1/2023

Belge Dili:

İngilizce

Document ID (Org No.):

2001284065

pISSN:

2536-4618