The solvatochromism and electronic structure of (E)-2-(2-hydroxystyryl)quinolin-8-ol

Ayşegül GÜMÜŞ; Yadigar Gülseven SIDIR; İsa SIDIR; Selçuk GÜMÜŞ

Makale detayları

The solvatochromism and electronic structure of (E)-2-(2-hydroxystyryl)quinolin-8-ol

Yazarlar:

Ayşegül GÜMÜŞ | Yadigar Gülseven SIDIR | İsa SIDIR | Selçuk GÜMÜŞ

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2019 Vol.43 Issue 6, pp.1503-1521

Belge Tipi:

Makale

Yayın Tarihi:

11/2019

Belge Dili:

İngilizce

Document ID (Org No.):

2000725513

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

The (E)-2-(2-hydroxystyryl)quinolin-8-ol (abbreviated as   HSQ) molecule was synthesized and characterized. The ESIPT, solvatochromism   properties, electronic structure, and ground and excited electric dipole   moments of this molecule were measured using absorption and fluorescence   spectra recorded in 13 different solvents. Its electronic structure via   electronic transitions was investigated to find the quantitative values of   solvatochromism properties by LSER calculations. The ESIPT mechanism was   clarified; ground and excited dipole moments were determined using   solvatochromic shift methods. The DFT (B3LYP)/6-311++++++G(d,p) method and   basis set with potential energy surface (PES) calculations of proton   transfer were used to explain the ESIPT mechanism. NBO analysis, NLO   properties, and behavior under an electric field were also determined.

Makale detayları

The solvatochromism and electronic structure of (E)-2-(2-hydroxystyryl)quinolin-8-ol

Yazarlar: Ayşegül GÜMÜŞ | Yadigar Gülseven SIDIR | İsa SIDIR | Selçuk GÜMÜŞ

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2019 Vol.43 Issue 6, pp.1503-1521

Belge Tipi: Makale

Yayın Tarihi: 11/2019

Belge Dili: İngilizce

Document ID (Org No.): 2000725513

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Ayşegül GÜMÜŞ | Yadigar Gülseven SIDIR | İsa SIDIR | Selçuk GÜMÜŞ

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2019 Vol.43 Issue 6, pp.1503-1521

Belge Tipi:

Makale

Yayın Tarihi:

11/2019

Belge Dili:

İngilizce

Document ID (Org No.):

2000725513

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527