Synthesis and characterization of transition metal coordination polymers derived from 1,4-benzenedicarboxylate and certain azoles

Aref A. M. ALY; Mahmoud A. GHANDOUR; Maged S. AL-FAKEH

Makale detayları

Synthesis and characterization of transition metal coordination polymers derived from 1,4-benzenedicarboxylate and certain azoles

Yazarlar:

Aref A. M. ALY | Mahmoud A. GHANDOUR | Maged S. AL-FAKEH

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2012 Vol.36 Issue 1, pp.69-79

Belge Tipi:

Makale

Yayın Tarihi:

12/2011

Belge Dili:

Türkçe

Document ID (Org No.):

2000727685

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

A series of coordination polymers of the general formula  {[M(BDC)(azoles)(H2O)m].xH2O}n (where M = Co(II), Ni(II), and  Cu(II); BDC = 1,4-benzenedicarboxylate; azoles = 2-aminobenzothiazole,  2-aminothiazole, and 2-amino-4-methyl-thiazole; m = 0 or 1; and x = 1  or 2) were prepared and characterized.  The complexes were  characterized based on elemental analysis, infrared and electronic  spectral studies, magnetic measurements, molar conductance, thermal  analysis, X-ray diffraction, scanning electron microscopy, and  biological activity.  Thermogravimetry, derivative thermogravimetry,  and differential thermal analysis were used to study the thermal  decomposition of the complexes.  The kinetic parameters were  calculated making use of the Coats-Redfern and Horowitz-Metzger  equations.

 

A series of coordination polymers of the general formula  {[M(BDC)(azoles)(H2O)m].xH2O}n (where M = Co(II), Ni(II), and  Cu(II); BDC = 1,4-benzenedicarboxylate; azoles = 2-aminobenzothiazole,  2-aminothiazole, and 2-amino-4-methyl-thiazole; m = 0 or 1; and x = 1  or 2) were prepared and characterized.  The complexes were  characterized based on elemental analysis, infrared and electronic  spectral studies, magnetic measurements, molar conductance, thermal  analysis, X-ray diffraction, scanning electron microscopy, and  biological activity.  Thermogravimetry, derivative thermogravimetry,  and differential thermal analysis were used to study the thermal  decomposition of the complexes.  The kinetic parameters were  calculated making use of the Coats-Redfern and Horowitz-Metzger  equations.

Makale detayları

Synthesis and characterization of transition metal coordination polymers derived from 1,4-benzenedicarboxylate and certain azoles

Yazarlar: Aref A. M. ALY | Mahmoud A. GHANDOUR | Maged S. AL-FAKEH

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2012 Vol.36 Issue 1, pp.69-79

Belge Tipi: Makale

Yayın Tarihi: 12/2011

Belge Dili: Türkçe

Document ID (Org No.): 2000727685

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Aref A. M. ALY | Mahmoud A. GHANDOUR | Maged S. AL-FAKEH

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2012 Vol.36 Issue 1, pp.69-79

Belge Tipi:

Makale

Yayın Tarihi:

12/2011

Belge Dili:

Türkçe

Document ID (Org No.):

2000727685

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527