SYNTHESIS OF NOVEL NAKED-EYE FE3+ CHEMOSENSING SILICA PARTICLES AND RH+3 COMPLEX BASED ON 4- 1H-IMIDAZO[4,5-F][1,10]PHENANTHROLINE-2YLPHENOL

Mehmet Ali ÖZLER; Said NADEEM

Makale detayları

SYNTHESIS OF NOVEL NAKED-EYE FE3+ CHEMOSENSING SILICA PARTICLES AND RH+3 COMPLEX BASED ON 4- 1H-IMIDAZO[4,5-F][1,10]PHENANTHROLINE-2YLPHENOL

Yazarlar:

Mehmet Ali ÖZLER | Said NADEEM

Yayıncı:

SciMatic

Ana Başlıklar:

Organik kimya

Dergi:

Journal of Ongoing Chemical Research 2015 Vol.2 Issue 1, pp.28-42

Belge Tipi:

Makale

Yayın Tarihi:

5/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000492393

Sıklık:

Yıllık

eISSN:

2651-4338

pISSN:

2651-4338

Özet:

 

A Rh3+ complex 4 derived from 4- 1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl phenol 3 was prepared at room temperature. 3 was stirred with pentamethylcyclopentadienlyrhodium chloride dimer for 30 minutes which resulted yellow precipitates which were washed with methanol, redissolved in acetone and purified chromatographically with ethanol. Phenanthroline-derived 3 was reacted with  3-chloropropyl trimethoxysilane to obtain an alkylated compound 5. Silica particles were functionalized by reacting with 5 at 70 oC in DMF for 6 h. Functionalized silica particles can be used for removal of different metals from aqueous and organic solutions and due to their bigger size can be easily filtered.

Makale detayları

SYNTHESIS OF NOVEL NAKED-EYE FE3+ CHEMOSENSING SILICA PARTICLES AND RH+3 COMPLEX BASED ON 4- 1H-IMIDAZO[4,5-F][1,10]PHENANTHROLINE-2YLPHENOL

Yazarlar: Mehmet Ali ÖZLER | Said NADEEM

Yayıncı: SciMatic

Ana Başlıklar: Organik kimya

Dergi: Journal of Ongoing Chemical Research 2015 Vol.2 Issue 1, pp.28-42

Belge Tipi: Makale

Yayın Tarihi: 5/2015

Belge Dili: İngilizce

Document ID (Org No.): 2000492393

Sıklık: Yıllık

eISSN: 2651-4338

pISSN: 2651-4338

Sayı

Yazarlar:

Mehmet Ali ÖZLER | Said NADEEM

Yayıncı:

SciMatic

Ana Başlıklar:

Organik kimya

Dergi:

Journal of Ongoing Chemical Research 2015 Vol.2 Issue 1, pp.28-42

Belge Tipi:

Makale

Yayın Tarihi:

5/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000492393

Sıklık:

Yıllık

eISSN:

2651-4338

pISSN:

2651-4338