Synthesis and Structural Characterization of Homo Dinuclear Phosphorus 1,1-Dithiolate Cd(II) Complexes

Ertuğrul Gazi Sağlam; Elif Bulat; Mustafa Saçmacı; Servet Yıldız

Makale detayları

Synthesis and Structural Characterization of Homo Dinuclear Phosphorus 1,1-Dithiolate Cd(II) Complexes

Yazarlar:

Ertuğrul Gazi Sağlam | Elif Bulat | Mustafa Saçmacı | Servet Yıldız

Yayıncı:

Duzce University

Ana Başlıklar:

Mühendislik

Dergi:

Düzce Üniversitesi Bilim ve Teknoloji Dergisi Vol.11 Issue 2, pp.759-774

Belge Tipi:

Makale

Yayın Tarihi:

4/2023

Belge Dili:

Türkçe

Document ID (Org No.):

2001288314

pISSN:

2148-2446

Anahtar kelimeler:

Özet:

 In this study, 2,4-bis3-methoxytolyl-1,3-dithia-2,4-diphosphetane-2,4-disulfide which is formulated as CH3C6H3OCH3-PSS2 compound was resynthesized. From this, two dithiophosphonic acids which were previously known were synthesized from the reaction of this compound with alcohols HS2PRORn, HLn; RCH3C6H3OCH3; R1 Ethyl-, L1; R2 2-propyl-, L2. These acids were converted to corresponding ammonium salts, NH4Ln. The ammonium salts were further reacted with CdCl2.H2O to prepare dinuclear three new dithiophosphonato cadmiumII complexes, Cdμ-Ln2Ln2 in ethanol medium. Structures of the complexes were characterized by elemental analysis, mass spectrometry ESI, FT-IR, Raman, NMR 1H, 13C, 31P spectroscopy.

 In this study, 2,4-bis3-methoxytolyl-1,3-dithia-2,4-diphosphetane-2,4-disulfide which is formulated as CH3C6H3OCH3-PSS2 compound was resynthesized. From this, two dithiophosphonic acids which were previously known were synthesized from the reaction of this compound with alcohols HS2PRORn, HLn; RCH3C6H3OCH3; R1 Ethyl-, L1; R2 2-propyl-, L2. These acids were converted to corresponding ammonium salts, NH4Ln. The ammonium salts were further reacted with CdCl2.H2O to prepare dinuclear three new dithiophosphonato cadmiumII complexes, Cdμ-Ln2Ln2 in ethanol medium. Structures of the complexes were characterized by elemental analysis, mass spectrometry ESI, FT-IR, Raman, NMR 1H, 13C, 31P spectroscopy.

 In this study, 2,4-bis3-methoxytolyl-1,3-dithia-2,4-diphosphetane-2,4-disulfide which is formulated as CH3C6H3OCH3-PSS2 compound was resynthesized. From this, two dithiophosphonic acids which were previously known were synthesized from the reaction of this compound with alcohols HS2PRORn, HLn; RCH3C6H3OCH3; R1 Ethyl-, L1; R2 2-propyl-, L2. These acids were converted to corresponding ammonium salts, NH4Ln. The ammonium salts were further reacted with CdCl2.H2O to prepare dinuclear three new dithiophosphonato cadmiumII complexes, Cdμ-Ln2Ln2 in ethanol medium. Structures of the complexes were characterized by elemental analysis, mass spectrometry ESI, FT-IR, Raman, NMR 1H, 13C, 31P spectroscopy.

 Bu çalışmada, 2,4-bis-3-metoksitolil-1,3-ditiya-2,4-difosfetan 2,4-disülfür CH3C6H3OCH3-PSS2 bileşiği yeniden sentezlendi. Bu bileşiğin alkollerle reaksiyonundan literatürde bilinen iki ditiyofosfonik asiti HS2PRORn, HLn; RCH3C6H3OCH3; R1 Etil-, L1, R2 2-propil-, L2 sentezlendi. Ham ditiyofosfonik asitler kuru amonyak gazıyla ligandlarına NH4S2PRORn dönüştürüldü. Etil alkol ortamında bu ligandların kadmiyum tuzlarıyla reaksiyonlarından çift çekirdekli yeni ditiyofosfonato CdII kompleksleri sentezlendi Cdμ-Ln2Ln2. Komplekslerin yapıları; elementel analizi, kütle spektrometresi ESI, FT-IR, Raman, NMR 1H, 13C, 31P spektroskopisiyle aydınlatıldı.

Makale detayları

Synthesis and Structural Characterization of Homo Dinuclear Phosphorus 1,1-Dithiolate Cd(II) Complexes

Yazarlar:

Ertuğrul Gazi Sağlam | Elif Bulat | Mustafa Saçmacı | Servet Yıldız

Yayıncı:

Duzce University

Ana Başlıklar:

Mühendislik

Dergi:

Düzce Üniversitesi Bilim ve Teknoloji Dergisi Vol.11 Issue 2, pp.759-774

Belge Tipi:

Makale

Yayın Tarihi:

4/2023

Belge Dili:

Türkçe

Document ID (Org No.):

2001288314

pISSN:

2148-2446

Phosphorus 1

1-Dithiolates

Dithiadiphosphetanes

Dithiophosphonic Acid

Cd(II)Dithiophosphonato ComplexesFosfor 1,1-Ditiyolatlar

Ditiyadifosfetanlar

Ditiyofosfonik Asit

Cd(II) Ditiyofosfonato Kompleksleri

Sayı

Makale detayları

Yazarlar: Ertuğrul Gazi Sağlam | Elif Bulat | Mustafa Saçmacı | Servet Yıldız

Yayıncı: Duzce University

Ana Başlıklar: Mühendislik

Dergi: Düzce Üniversitesi Bilim ve Teknoloji Dergisi Vol.11 Issue 2, pp.759-774

Belge Tipi: Makale

Yayın Tarihi: 4/2023

Belge Dili: Türkçe

Document ID (Org No.): 2001288314

pISSN: 2148-2446

Sayı

Yazarlar:

Ertuğrul Gazi Sağlam | Elif Bulat | Mustafa Saçmacı | Servet Yıldız

Yayıncı:

Duzce University

Ana Başlıklar:

Mühendislik

Dergi:

Düzce Üniversitesi Bilim ve Teknoloji Dergisi Vol.11 Issue 2, pp.759-774

Belge Tipi:

Makale

Yayın Tarihi:

4/2023

Belge Dili:

Türkçe

Document ID (Org No.):

2001288314

pISSN:

2148-2446