Reduction Of Some Dithiophosphonates In Aprotic Media On Freshly Copper Plated Glassy Carbon Electrode

P. ÇEKİRDEK; A.o. SOLAK; A. AYDİN; H. YİLMAZ

Makale detayları

Reduction Of Some Dithiophosphonates In Aprotic Media On Freshly Copper Plated Glassy Carbon Electrode

Yazarlar:

P. ÇEKİRDEK | A.o. SOLAK | A. AYDİN | H. YİLMAZ

Yayıncı:

Kyrgyz-Turkish Manas University

Dergi:

Manas Journal of Natural Sciences 2011 Vol.2 Issue 12, pp.1-16

Belge Tipi:

Makale

Yayın Tarihi:

12/2010

Belge Dili:

İngilizce

Document ID (Org No.):

2000528258

Sıklık:

İki Yıllık

eISSN:

1694-7398

pISSN:

1694-7398

Özet:

 

Dithiophosphonates are reduced electrochemically with two electron transfer in acetonitrile containing 0.1 M tetrabutylammonium tetrafluoroborate  TBATFB  at a freshly copper plated GC electrode. The peaks for all of the dithiophosphonate derivatives were observed at about –1.5 V  vs. Ag/Ag+  at copper plated GC electrode. Data revealed that the reduction process on copper electrode was irreversible and followed by EC mechanism. The diffusion coefficients and numbers of electrons transferred were found by UME electrode using Baranski method. The adsorption tests were applied to examine the adsorption characteristics of the derivatives under investigation. Simulation CV voltammograms of dithiophosphonates were acquired by DigiSim® 3.03 version and compared with the experimental voltammograms to calculate the chemical and electrochemical constants.

Makale detayları

Reduction Of Some Dithiophosphonates In Aprotic Media On Freshly Copper Plated Glassy Carbon Electrode

Yazarlar: P. ÇEKİRDEK | A.o. SOLAK | A. AYDİN | H. YİLMAZ

Yayıncı: Kyrgyz-Turkish Manas University

Dergi: Manas Journal of Natural Sciences 2011 Vol.2 Issue 12, pp.1-16

Belge Tipi: Makale

Yayın Tarihi: 12/2010

Belge Dili: İngilizce

Document ID (Org No.): 2000528258

Sıklık: İki Yıllık

eISSN: 1694-7398

pISSN: 1694-7398

Sayı

Yazarlar:

P. ÇEKİRDEK | A.o. SOLAK | A. AYDİN | H. YİLMAZ

Yayıncı:

Kyrgyz-Turkish Manas University

Dergi:

Manas Journal of Natural Sciences 2011 Vol.2 Issue 12, pp.1-16

Belge Tipi:

Makale

Yayın Tarihi:

12/2010

Belge Dili:

İngilizce

Document ID (Org No.):

2000528258

Sıklık:

İki Yıllık

eISSN:

1694-7398

pISSN:

1694-7398