Theoretical calculations of some new N-(α,β-Unsaturated acyl)sulfonamides and an investigation on correlations with those experimental values

Süreyya Musalli

doi:https://doi.org/10.17678/beujst.39968

Makale detayları

Theoretical calculations of some new N-(α,β-Unsaturated acyl)sulfonamides and an investigation on correlations with those experimental values

Yazarlar:

Süreyya Musalli

Yayıncı:

Bitlis Eren University

Dergi:

Bitlis Eren University Journal of Science and Technology 2014 Vol.4 Issue 2, pp.26-30

Belge Tipi:

Makale

Yayın Tarihi:

2/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000888110

Sıklık:

İki Yıllık

eISSN:

2146-7706

DOI:

https://doi.org/10.17678/beujst.39968

Özet:

 


Previously some new N-(α,β-Unsaturated acyl)sulfonamides are prepared (i) by the N-acylation of sulfonamides with N-(α,β-unsaturated acyl)benzotriazoles in the presence of potassium tert-butoxide and (ii) by reactions of appropriate α,β-unsaturated carboxamides with sulfonylbenzotriazoles in the presence of sodium hydride. The reaction efficiency has been changed related to route i or ii. Certain theoretical properties of N-(α,β-Unsaturated acyl)sulfonamides and reactants were calculated in Gaussian09 program using DFT method at B3LYP/6-311+g(d,p) level of theory. The theoretical data was then compared with certain experimental results. 

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Makale detayları

Theoretical calculations of some new N-(α,β-Unsaturated acyl)sulfonamides and an investigation on correlations with those experimental values

Yazarlar: Süreyya Musalli

Yayıncı: Bitlis Eren University

Dergi: Bitlis Eren University Journal of Science and Technology 2014 Vol.4 Issue 2, pp.26-30

Belge Tipi: Makale

Yayın Tarihi: 2/2015

Belge Dili: İngilizce

Document ID (Org No.): 2000888110

Sıklık: İki Yıllık

eISSN: 2146-7706

DOI: https://doi.org/10.17678/beujst.39968

Sayı

Yazarlar:

Süreyya Musalli

Yayıncı:

Bitlis Eren University

Dergi:

Bitlis Eren University Journal of Science and Technology 2014 Vol.4 Issue 2, pp.26-30

Belge Tipi:

Makale

Yayın Tarihi:

2/2015

Belge Dili:

İngilizce

Document ID (Org No.):

2000888110

Sıklık:

İki Yıllık

eISSN:

2146-7706

DOI:

https://doi.org/10.17678/beujst.39968