Investigation of Gas Storage Properties of Metal Complexes Including Dicarboxylic Acid Moities

Özlem Erdem; Emel Yildiz

Makale detayları

Investigation of Gas Storage Properties of Metal Complexes Including Dicarboxylic Acid Moities

Yazarlar:

Özlem Erdem | Emel Yildiz

Yayıncı:

İlker ÖRS

Dergi:

International Journal of Energy Applications and Technologies 2015 Vol.2 Issue 1, pp.8-10

Belge Tipi:

Makale

Yayın Tarihi:

5/2015

Belge Dili:

Türkçe

Document ID (Org No.):

2000719097

Sıklık:

Üç Aylık

eISSN:

2548-060X

Özet:

 

The metal complexes of dicarboxylic acid derivatives were synthesized and their gas-storage properties were characterized. Metal complexes displaying various metal-organic frameworks with 4,5-imidazole-dicarboxylic acid ligand (L) with  Mo(III), W(VI), Ce(III), Sm(III), and Sn(IV) were synthesized in order to examine their gas adsorption properties. The porous complexes were characterized by elemental analysis, FT-IR, 1H-NMR, spectroscopic methods and microanalysis. Investigation of the structures of these complexes indicates that gases are most probably occluded in homogeneous and linear micropores which are composed of micropore units surrounded by dicarboxylate bridges. Gas storage and adsorption properties of these complexes were investigated via BET measurements. Sorption property of H2 and N2 was performed at temperature of 298 K and pressure of 1 bar.

Makale detayları

Investigation of Gas Storage Properties of Metal Complexes Including Dicarboxylic Acid Moities

Yazarlar: Özlem Erdem | Emel Yildiz

Yayıncı: İlker ÖRS

Dergi: International Journal of Energy Applications and Technologies 2015 Vol.2 Issue 1, pp.8-10

Belge Tipi: Makale

Yayın Tarihi: 5/2015

Belge Dili: Türkçe

Document ID (Org No.): 2000719097

Sıklık: Üç Aylık

eISSN: 2548-060X

Sayı

Yazarlar:

Özlem Erdem | Emel Yildiz

Yayıncı:

İlker ÖRS

Dergi:

International Journal of Energy Applications and Technologies 2015 Vol.2 Issue 1, pp.8-10

Belge Tipi:

Makale

Yayın Tarihi:

5/2015

Belge Dili:

Türkçe

Document ID (Org No.):

2000719097

Sıklık:

Üç Aylık

eISSN:

2548-060X