Poly(aniline-co-N-methylpyrrole) and Poly(N-methylpyrrole-co-N-methylaniline) Synthesized on ZnNi Coated Carbon Steel Surface

Abdurrahman Akdağ

Makale detayları

Poly(aniline-co-N-methylpyrrole) and Poly(N-methylpyrrole-co-N-methylaniline) Synthesized on ZnNi Coated Carbon Steel Surface

Yazarlar:

Abdurrahman Akdağ

Yayıncı:

Osmaniye Korkut Ata Üniversitesi

Ana Başlıklar:

Elektrokimyasal Teknolojiler

Dergi:

Osmaniye Korkut Ata Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.8 Issue 1, pp.314-324

Belge Tipi:

Makale

Yayın Tarihi:

1/2025

Belge Dili:

Türkçe

Document ID (Org No.):

2001330035

pISSN:

2687-3729

Anahtar kelimeler:

Özet:

 Polyaniline-co-N-methylpyrrole and polyN-methylpyrrole-co-N-methylaniline copolymers were synthesized on the ZnNi-coated carbon steel CSZnNi electrode surface by cyclic voltammetry method. Copolymer film-coated electrodes were characterized by anodic polarization, linear sweep voltammetry and electrochemical impedance spectroscopy. It was determined that there was a ZnNi alloy underlying the copolymer films synthesized by linear sweep voltammetry. Anodic polarization curves showed that the current values of the polyN-methylpyrrole-co-N-methylaniline coated CSZnNi electrode were lower than the polyaniline-co-N-methylpyrrole coated CSZnNi electrode. Electrochemical impedance spectroscopy results showed that the polarization resistance of the polyN-methylpyrrole-co-N-methylaniline coated CSZnNi electrode was higher than the polyaniline-co-N-methylpyrrole coated CSZnNi electrode after a long waiting time of 168 hours in a corrosive environment.

 Polyaniline-co-N-methylpyrrole and polyN-methylpyrrole-co-N-methylaniline copolymers were synthesized on the ZnNi-coated carbon steel CSZnNi electrode surface by cyclic voltammetry method. Copolymer film-coated electrodes were characterized by anodic polarization, linear sweep voltammetry and electrochemical impedance spectroscopy. It was determined that there was a ZnNi alloy underlying the copolymer films synthesized by linear sweep voltammetry. Anodic polarization curves showed that the current values of the polyN-methylpyrrole-co-N-methylaniline coated CSZnNi electrode were lower than the polyaniline-co-N-methylpyrrole coated CSZnNi electrode. Electrochemical impedance spectroscopy results showed that the polarization resistance of the polyN-methylpyrrole-co-N-methylaniline coated CSZnNi electrode was higher than the polyaniline-co-N-methylpyrrole coated CSZnNi electrode after a long waiting time of 168 hours in a corrosive environment.

 Polyaniline-co-N-methylpyrrole and polyN-methylpyrrole-co-N-methylaniline copolymers were synthesized on the ZnNi-coated carbon steel CSZnNi electrode surface by cyclic voltammetry method. Copolymer film-coated electrodes were characterized by anodic polarization, linear sweep voltammetry and electrochemical impedance spectroscopy. It was determined that there was a ZnNi alloy underlying the copolymer films synthesized by linear sweep voltammetry. Anodic polarization curves showed that the current values of the polyN-methylpyrrole-co-N-methylaniline coated CSZnNi electrode were lower than the polyaniline-co-N-methylpyrrole coated CSZnNi electrode. Electrochemical impedance spectroscopy results showed that the polarization resistance of the polyN-methylpyrrole-co-N-methylaniline coated CSZnNi electrode was higher than the polyaniline-co-N-methylpyrrole coated CSZnNi electrode after a long waiting time of 168 hours in a corrosive environment.

 Polianilin-ko-N-metilpirol ve poliN-metilpirol-ko-N-metilanilin kopolimerleri ZnNi kaplı karbon çelik CSZnNi elektrot yüzeyine döngülü voltametri yöntemiyle sentezlenmiştir. Kopolimer film kaplı elektrotlar anodik polarizasyon, doğrusal taramalı voltametri ve elektrokimyasal empedans spektroskopisi ile karakterize edilmiştir. Doğrusal taramalı voltametri ile sentezlenen kopolimer filmlerin altında ZnNi alaşımı bulunduğu belirlenmiştir. Anodik polazrizasyon eğrileri poliN-metilpirol-ko-N-metilanilin kaplı CSZnNi elektrodun akım değerlerinin daha düşük olduğu göstermiştir. Elektrokimyasal empedans spektroskopisi korozif ortamda uzun bekleme süresi olan 168 saat sonunda poliN-metilpirol-ko-N-metilanilin kaplı CSZnNi elektrodun polarizasyon direncinin Polianilin-ko-N-metilpirol kaplı elektroda göre daha yüksek olduğunu göstermiştir.

Makale detayları

Poly(aniline-co-N-methylpyrrole) and Poly(N-methylpyrrole-co-N-methylaniline) Synthesized on ZnNi Coated Carbon Steel Surface

Yazarlar:

Abdurrahman Akdağ

Yayıncı:

Osmaniye Korkut Ata Üniversitesi

Ana Başlıklar:

Elektrokimyasal Teknolojiler

Dergi:

Osmaniye Korkut Ata Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.8 Issue 1, pp.314-324

Belge Tipi:

Makale

Yayın Tarihi:

1/2025

Belge Dili:

Türkçe

Document ID (Org No.):

2001330035

pISSN:

2687-3729

ZnNi

impedance

voltammetry

poly(aniline-co-N-methylpyrrole)

poly(N-methylpyrrole-co-N-methylaniline)ZnNi

empedans

voltametri

Poli(anilin-ko-N-metilpirol)

poli(N-metilpirol-ko-N-metilanilin)

Sayı

Makale detayları

Yazarlar: Abdurrahman Akdağ

Yayıncı: Osmaniye Korkut Ata Üniversitesi

Ana Başlıklar: Elektrokimyasal Teknolojiler

Dergi: Osmaniye Korkut Ata Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.8 Issue 1, pp.314-324

Belge Tipi: Makale

Yayın Tarihi: 1/2025

Belge Dili: Türkçe

Document ID (Org No.): 2001330035

pISSN: 2687-3729

Sayı

Yazarlar:

Abdurrahman Akdağ

Yayıncı:

Osmaniye Korkut Ata Üniversitesi

Ana Başlıklar:

Elektrokimyasal Teknolojiler

Dergi:

Osmaniye Korkut Ata Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.8 Issue 1, pp.314-324

Belge Tipi:

Makale

Yayın Tarihi:

1/2025

Belge Dili:

Türkçe

Document ID (Org No.):

2001330035

pISSN:

2687-3729