Synthesis And Characterization of Two New Hofmann-Type-Like Compounds From Some Alkali Metal Atoms And Glycine Anhydride

Zeki Kartal; Zarife Sibel Şahin

Makale detayları

Synthesis And Characterization of Two New Hofmann-Type-Like Compounds From Some Alkali Metal Atoms And Glycine Anhydride

Yazarlar:

Zeki Kartal | Zarife Sibel Şahin

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Crystallography

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 1, pp.125-136

Belge Tipi:

Makale

Yayın Tarihi:

4/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001303748

pISSN:

2149-0120

Anahtar kelimeler:

Özet:

 In this study, two new compounds with their closed formula, C8H10K2N6NiO4, and C8H10Na2N6NiO4, were synthesized, the first in crystal form and the second in powder form. Various properties of these compounds were characterized by SC-XRD and FT-IR methods. Theoretical information about the compounds was obtained with the help of the Gaussian 03 program. The molecular formula that best reflects the structural properties of this first 3D compound, which is in crystalline form and has polymeric properties, can be given as K2GAH2O2NiCN4n. With a similar thought, it can be suggested that the molecular formula that best reflects the structural properties of the second 3D compound in powder form and with polymeric properties will be Na2GAH2O2NiCN4n. The asymmetric unit of the K2GAH2O2Niμ4-CN4n compound is composed of a half NiII ion, one KI cation, two cyanide ligands, a half GA ligand molecule, and one bounded water ligand molecule. The structure of the compound, which consists of 3D polymeric chains, is formed by various bonds between the GA molecule, KI cations, water ligand molecules, and NiCN4 ions.

 In this study, two new compounds with their closed formula, C8H10K2N6NiO4, and C8H10Na2N6NiO4, were synthesized, the first in crystal form and the second in powder form. Various properties of these compounds were characterized by SC-XRD and FT-IR methods. Theoretical information about the compounds was obtained with the help of the Gaussian 03 program. The molecular formula that best reflects the structural properties of this first 3D compound, which is in crystalline form and has polymeric properties, can be given as K2GAH2O2NiCN4n. With a similar thought, it can be suggested that the molecular formula that best reflects the structural properties of the second 3D compound in powder form and with polymeric properties will be Na2GAH2O2NiCN4n. The asymmetric unit of the K2GAH2O2Niμ4-CN4n compound is composed of a half NiII ion, one KI cation, two cyanide ligands, a half GA ligand molecule, and one bounded water ligand molecule. The structure of the compound, which consists of 3D polymeric chains, is formed by various bonds between the GA molecule, KI cations, water ligand molecules, and NiCN4 ions.

 In this study, two new compounds with their closed formula, C8H10K2N6NiO4, and C8H10Na2N6NiO4, were synthesized, the first in crystal form and the second in powder form. Various properties of these compounds were characterized by SC-XRD and FT-IR methods. Theoretical information about the compounds was obtained with the help of the Gaussian 03 program. The molecular formula that best reflects the structural properties of this first 3D compound, which is in crystalline form and has polymeric properties, can be given as K2GAH2O2NiCN4n. With a similar thought, it can be suggested that the molecular formula that best reflects the structural properties of the second 3D compound in powder form and with polymeric properties will be Na2GAH2O2NiCN4n. The asymmetric unit of the K2GAH2O2Niμ4-CN4n compound is composed of a half NiII ion, one KI cation, two cyanide ligands, a half GA ligand molecule, and one bounded water ligand molecule. The structure of the compound, which consists of 3D polymeric chains, is formed by various bonds between the GA molecule, KI cations, water ligand molecules, and NiCN4 ions.

 In this study, two new compounds with their closed formula, C8H10K2N6NiO4, and C8H10Na2N6NiO4, were synthesized, the first in crystal form and the second in powder form. Various properties of these compounds were characterized by SC-XRD and FT-IR methods. Theoretical information about the compounds was obtained with the help of the Gaussian 03 program. The molecular formula that best reflects the structural properties of this first 3D compound, which is in crystalline form and has polymeric properties, can be given as K2GAH2O2NiCN4n. With a similar thought, it can be suggested that the molecular formula that best reflects the structural properties of the second 3D compound in powder form and with polymeric properties will be Na2GAH2O2NiCN4n. The asymmetric unit of the K2GAH2O2Niμ4-CN4n compound is composed of a half NiII ion, one KI cation, two cyanide ligands, a half GA ligand molecule, and one bounded water ligand molecule. The structure of the compound, which consists of 3D polymeric chains, is formed by various bonds between the GA molecule, KI cations, water ligand molecules, and NiCN4 ions.

Makale detayları

Synthesis And Characterization of Two New Hofmann-Type-Like Compounds From Some Alkali Metal Atoms And Glycine Anhydride

Yazarlar:

Zeki Kartal | Zarife Sibel Şahin

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Crystallography

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 1, pp.125-136

Belge Tipi:

Makale

Yayın Tarihi:

4/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001303748

pISSN:

2149-0120

Hofmann-type-like compounds

Glycine anhydride

SC-XRD

DFT

FT-IR spectra

Sayı

Makale detayları

Synthesis And Characterization of Two New Hofmann-Type-Like Compounds From Some Alkali Metal Atoms And Glycine Anhydride

Yazarlar: Zeki Kartal | Zarife Sibel Şahin

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Crystallography

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 1, pp.125-136

Belge Tipi: Makale

Yayın Tarihi: 4/2024

Belge Dili: İngilizce

Document ID (Org No.): 2001303748

pISSN: 2149-0120

Hofmann-type-like compounds

Glycine anhydride

SC-XRD

DFT

FT-IR spectra

Sayı

Yazarlar:

Zeki Kartal | Zarife Sibel Şahin

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Crystallography

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry Vol.11 Issue 1, pp.125-136

Belge Tipi:

Makale

Yayın Tarihi:

4/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001303748

pISSN:

2149-0120