AN OXOVANADIUM(IV)-CONTAINING N2O2 CHELATE COMPLEX; CRYSTAL STRUCTURE DETERMINATION AND DFT

Berat İLHAN CEYLAN

doi:https://doi.org/10.18596/jotcsa.33245

Makale detayları

AN OXOVANADIUM(IV)-CONTAINING N2O2 CHELATE COMPLEX; CRYSTAL STRUCTURE DETERMINATION AND DFT

Yazarlar:

Berat İLHAN CEYLAN

Yayıncı:

Turkish Chemical Society

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2016 Vol.3 Issue 3, pp.393-402

Belge Tipi:

Makale

Yayın Tarihi:

1/2017

Belge Dili:

Türkçe

Document ID (Org No.):

2000503812

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.33245

Özet:

 


A stable oxovanadium(IV) complex was obtained by template condensation of 2-hydroxynaphthaldehyde S-methylthiosemicarbazone and salicylaldehyde in the presence of VOSO4. The structure of  VO(II) centered metal complex was confirmed  by elemental analysis and was characterized by single crystal X-ray diffraction technique and density functional theory (DFT/B3LYP) LANL2DZ compared with experimental data. The complex crystal is in the form of dark green-colored small sticks. The experimental data of the monoclinic crystalline structure which belonging P1 21/n1 space group was compared to those obtained with DFT-B3LYP-LANDL2DZ. It was seen that experimental and theoretical values are in a good agreement. 

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Makale detayları

AN OXOVANADIUM(IV)-CONTAINING N2O2 CHELATE COMPLEX; CRYSTAL STRUCTURE DETERMINATION AND DFT

Yazarlar: Berat İLHAN CEYLAN

Yayıncı: Turkish Chemical Society

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2016 Vol.3 Issue 3, pp.393-402

Belge Tipi: Makale

Yayın Tarihi: 1/2017

Belge Dili: Türkçe

Document ID (Org No.): 2000503812

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.33245

Sayı

Yazarlar:

Berat İLHAN CEYLAN

Yayıncı:

Turkish Chemical Society

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2016 Vol.3 Issue 3, pp.393-402

Belge Tipi:

Makale

Yayın Tarihi:

1/2017

Belge Dili:

Türkçe

Document ID (Org No.):

2000503812

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.33245