The Direct Electrochemical Synthesis of Ti(II), Fe(II), Cd(II), Sn(II), and Pb(II) Complexes with N, N -Bis(Salicylidene)-o-Phenylenediamine

Jianning LIU; Bing ZHANG; Bowan WU; Kejun ZHANG; Shenli HU

Makale detayları

The Direct Electrochemical Synthesis of Ti(II), Fe(II), Cd(II), Sn(II), and Pb(II) Complexes with N, N -Bis(Salicylidene)-o-Phenylenediamine

Yazarlar:

Jianning LIU | Bing ZHANG | Bowan WU | Kejun ZHANG | Shenli HU

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2007 Vol.31 Issue 6, pp.623-629

Belge Tipi:

Makale

Yayın Tarihi:

5/2007

Belge Dili:

İngilizce

Document ID (Org No.):

2000728599

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

The electrochemical oxidation of anodic Ti, Fe, Cd, Sn, and  Pb (=M) into acetonitrile solutions of  N,N'-bis(salicylidene)-o-phenylenediamine [SalophH2] gives the  corresponding M(Saloph) complexes in high yield.  The mechanism of the  electrochemical reactions is discussed.  SalophH2 forms complexes  (1:1 molar ratio) with titanium, iron, cadmium, tin, and lead ions.   The complexes have been characterized by elemental analyses, molar  conductivity measurements, and infrared and electronic spectral data.   The SalophH2 complexes of iron(II) and cadmium(II) have been further  identified by 1H-NMR and mass spectra.

 

The electrochemical oxidation of anodic Ti, Fe, Cd, Sn, and  Pb (=M) into acetonitrile solutions of  N,N'-bis(salicylidene)-o-phenylenediamine [SalophH2] gives the  corresponding M(Saloph) complexes in high yield.  The mechanism of the  electrochemical reactions is discussed.  SalophH2 forms complexes  (1:1 molar ratio) with titanium, iron, cadmium, tin, and lead ions.   The complexes have been characterized by elemental analyses, molar  conductivity measurements, and infrared and electronic spectral data.   The SalophH2 complexes of iron(II) and cadmium(II) have been further  identified by 1H-NMR and mass spectra.

Makale detayları

The Direct Electrochemical Synthesis of Ti(II), Fe(II), Cd(II), Sn(II), and Pb(II) Complexes with N, N -Bis(Salicylidene)-o-Phenylenediamine

Yazarlar: Jianning LIU | Bing ZHANG | Bowan WU | Kejun ZHANG | Shenli HU

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2007 Vol.31 Issue 6, pp.623-629

Belge Tipi: Makale

Yayın Tarihi: 5/2007

Belge Dili: İngilizce

Document ID (Org No.): 2000728599

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Jianning LIU | Bing ZHANG | Bowan WU | Kejun ZHANG | Shenli HU

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2007 Vol.31 Issue 6, pp.623-629

Belge Tipi:

Makale

Yayın Tarihi:

5/2007

Belge Dili:

İngilizce

Document ID (Org No.):

2000728599

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527