Utilization of FTIR Spectroscopic Method in Classification and Analysis of Mineral Samples Containing Sodium and Potassium

Fahriye Öğüt; Adnan Kenar

Makale detayları

Utilization of FTIR Spectroscopic Method in Classification and Analysis of Mineral Samples Containing Sodium and Potassium

Yazarlar:

Fahriye Öğüt | Adnan Kenar

Yayıncı:

Duzce University

Ana Başlıklar:

Mühendislik

Dergi:

Düzce Üniversitesi Bilim ve Teknoloji Dergisi Vol.12 Issue 1, pp.602-611

Belge Tipi:

Makale

Yayın Tarihi:

1/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001310355

pISSN:

2148-2446

Anahtar kelimeler:

Özet:

 Feldspar is used as an important raw material in the ceramic, porcelain, and glass industries and as a filling material in the welding electrode, rubber, plastic, and paint industries. The ratio of Na2O originated from Na-feldspar and K2O originated from K-feldspar in feldspar plays a decisive role in many issues, from melting points to usage areas. However, since Na-feldspar and K-feldspar have similar physicochemical properties, it is difficult to separate and analyze them from their natural mineral environment by traditional methods. For this reason, it has become necessary to choose a method that can be applied without separating feldspar species from each other and without damaging the sample. The ATR-FTIR method was preferred because of its ease of sample preparation, measurement without damaging the sample, and providing information about the functional groups and other components in the sample. In this study, using ATR-FTIR attenuated total reflectance- fourier transform infrared spectroscopy and multivariate statistical techniques, the percentages of Na2O and K2O in feldspar samples were analyzed in a natural matrix environment without any pretreatment, and Na-feldspar and K-feldspar samples were grouped.

 Feldspar is used as an important raw material in the ceramic, porcelain, and glass industries and as a filling material in the welding electrode, rubber, plastic, and paint industries. The ratio of Na2O originated from Na-feldspar and K2O originated from K-feldspar in feldspar plays a decisive role in many issues, from melting points to usage areas. However, since Na-feldspar and K-feldspar have similar physicochemical properties, it is difficult to separate and analyze them from their natural mineral environment by traditional methods. For this reason, it has become necessary to choose a method that can be applied without separating feldspar species from each other and without damaging the sample. The ATR-FTIR method was preferred because of its ease of sample preparation, measurement without damaging the sample, and providing information about the functional groups and other components in the sample. In this study, using ATR-FTIR attenuated total reflectance- fourier transform infrared spectroscopy and multivariate statistical techniques, the percentages of Na2O and K2O in feldspar samples were analyzed in a natural matrix environment without any pretreatment, and Na-feldspar and K-feldspar samples were grouped.

 Feldspar is used as an important raw material in the ceramic, porcelain, and glass industries and as a filling material in the welding electrode, rubber, plastic, and paint industries. The ratio of Na2O originated from Na-feldspar and K2O originated from K-feldspar in feldspar plays a decisive role in many issues, from melting points to usage areas. However, since Na-feldspar and K-feldspar have similar physicochemical properties, it is difficult to separate and analyze them from their natural mineral environment by traditional methods. For this reason, it has become necessary to choose a method that can be applied without separating feldspar species from each other and without damaging the sample. The ATR-FTIR method was preferred because of its ease of sample preparation, measurement without damaging the sample, and providing information about the functional groups and other components in the sample. In this study, using ATR-FTIR attenuated total reflectance- fourier transform infrared spectroscopy and multivariate statistical techniques, the percentages of Na2O and K2O in feldspar samples were analyzed in a natural matrix environment without any pretreatment, and Na-feldspar and K-feldspar samples were grouped.

 Feldispat, seramik, porselen ve cam sanayinde önemli bir hammadde olarak; kaynak elektrodu, kauçuk, plastik ve boya sanayinde dolgu malzemesi olarak kullanılmaktadır. Feldispatın içerdiği Na2O Na-feldspat kaynaklı ve K2O K-feldspat kaynaklı oranı, erime noktasından kullanım alanlarına kadar birçok konuda belirleyici rol oynamaktadır. Fakat Na-feldspat ve K-feldspat benzer fizikokimyasal özelliklere sahip olmaları nedeniyle bulundukları doğal mineral ortamından geleneksel yöntemlerle ayrılıp analiz edilmesi güçtür. Bu nedenle feldispat türlerini birbirinden ayırmadan ve numuneye zarar vermeden uygulanabilecek bir yöntem seçilmesi gerekliliği ortaya çıkmıştır. ATR- FTIR yöntemi örnek hazırlama kolaylığı, numuneye zarar vermeden ölçüm yapılabilmesi ve numunedeki fonsiyonel gruplar ve diğer bileşenler hakkında bilgi vermesi nedeniyle tercih edilmiştir. Bu çalışmada ATR-FTIR Fourier dönüşümlü kızılötesi-azaltılmış toplam yansıma spektroskopisi ve çok değişkenli istatistiksel teknikler kullanılarak feldspat numunelerindeki Na2O ve K2O yüzdeleri hiçbir ön işlem uygulamadan, doğal ortamında analiz edilmiştir. Na-feldspat ve K-feldspat numuneleri sınıflandırılmıştır.

Makale detayları

Utilization of FTIR Spectroscopic Method in Classification and Analysis of Mineral Samples Containing Sodium and Potassium

Yazarlar:

Fahriye Öğüt | Adnan Kenar

Yayıncı:

Duzce University

Ana Başlıklar:

Mühendislik

Dergi:

Düzce Üniversitesi Bilim ve Teknoloji Dergisi Vol.12 Issue 1, pp.602-611

Belge Tipi:

Makale

Yayın Tarihi:

1/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001310355

pISSN:

2148-2446

ATR-FTIR spectroscopy

multivariate analysis

chemometry

feldsparATR-FTIR spektroskopisi

çok değişkenli analiz

kemometri

feldispat

Sayı

Makale detayları

Yazarlar: Fahriye Öğüt | Adnan Kenar

Yayıncı: Duzce University

Ana Başlıklar: Mühendislik

Dergi: Düzce Üniversitesi Bilim ve Teknoloji Dergisi Vol.12 Issue 1, pp.602-611

Belge Tipi: Makale

Yayın Tarihi: 1/2024

Belge Dili: İngilizce

Document ID (Org No.): 2001310355

pISSN: 2148-2446

Sayı

Yazarlar:

Fahriye Öğüt | Adnan Kenar

Yayıncı:

Duzce University

Ana Başlıklar:

Mühendislik

Dergi:

Düzce Üniversitesi Bilim ve Teknoloji Dergisi Vol.12 Issue 1, pp.602-611

Belge Tipi:

Makale

Yayın Tarihi:

1/2024

Belge Dili:

İngilizce

Document ID (Org No.):

2001310355

pISSN:

2148-2446