NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION

Yasemin SÜZEN; Simge METİNOĞLU

doi:https://doi.org/10.18038/aubtda.312012

Makale detayları

NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION

Yazarlar:

Yasemin SÜZEN | Simge METİNOĞLU

Yayıncı:

Eskisehir Technical University

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 2017 Vol.18 Issue 5, pp.973-987

Belge Tipi:

Makale

Yayın Tarihi:

12/2017

Belge Dili:

Türkçe

Document ID (Org No.):

2000417106

pISSN:

2667-4211

DOI:

https://doi.org/10.18038/aubtda.312012

Özet:

 


In this
article, highly cross-linked inorganic and organic hybrid polyphosphazene
microspheres including amino groups on the surface have been successfully
obtained via self-assembly polycondensation approach using 4,4ʹ-diaminodiphenylmethane
and octachlorocyclotetraphosphazene which is a new crosslinker. Experiments
were performed without adding a surfactant or stabilizer, using only an
ultrasonic bath. Otherwise, effect of different molar ratios of the reactants,
reaction time and ultrasonic power were investigated on preparing
morphologically good spheres. The reactivity of octachlorocyclotetraphosphazene
was investigated comparing with hexachlorocyclotriphosphazene which is the most
popular crosslinker cyclic phosphazene molecule. The size of acquired microspheres
were approximately same, and 1.00μm. The novel microspheres were characterized
by SEM, FTIR, ZETA, UV, Fluorescense, XRD and TGA.


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Makale detayları

NOVEL CYCLOMATRIX-TYPE POLYPHOSPHAZENE MICROSPHERES CROSSLINKED WITH OCTACHLOROCYCLOTETRAPHOSPHAZENE: PREPARATION AND CHARACTERIZATION

Yazarlar: Yasemin SÜZEN | Simge METİNOĞLU

Yayıncı: Eskisehir Technical University

Ana Başlıklar: Uygulamalı fizik

Dergi: Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 2017 Vol.18 Issue 5, pp.973-987

Belge Tipi: Makale

Yayın Tarihi: 12/2017

Belge Dili: Türkçe

Document ID (Org No.): 2000417106

pISSN: 2667-4211

DOI: https://doi.org/10.18038/aubtda.312012

Sayı

Yazarlar:

Yasemin SÜZEN | Simge METİNOĞLU

Yayıncı:

Eskisehir Technical University

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 2017 Vol.18 Issue 5, pp.973-987

Belge Tipi:

Makale

Yayın Tarihi:

12/2017

Belge Dili:

Türkçe

Document ID (Org No.):

2000417106

pISSN:

2667-4211

DOI:

https://doi.org/10.18038/aubtda.312012