Synthesis and characterization of Ni(II) and Cu(II) complexes derived from novel phenolic Mannich bases

Nurgün BÜYÜKKIDAN; Salih ÖZER

Makale detayları

Synthesis and characterization of Ni(II) and Cu(II) complexes derived from novel phenolic Mannich bases

Yazarlar:

Nurgün BÜYÜKKIDAN | Salih ÖZER

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2013 Vol.37 Issue 1, pp.101-110

Belge Tipi:

Makale

Yayın Tarihi:

12/2012

Belge Dili:

Türkçe

Document ID (Org No.):

2000727494

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

The novel phenolic Mannich bases 2,2'-(2-hydroxy-4,5-  dimethylbenzylazanediyl)diethanol (1) and 2-((2-(4-(2-hydroxy-4,5-  dimethylbenzyl)piperazin-1-yl)ethylamino)methyl)-4,5-dimethylphenol  (2) have been synthesized in good yield by using a microwave-induced  technique from 3,4-dimethylphenol and corresponding amines in the  presence of formaldehyde.  Metal complexes of 1 and 2 for Ni(II) (3  and 5) and for Cu(II) (4 and 6) have also been prepared and all  compounds have been characterized by elemental and spectral analyses.  Thermal, magnetic, and electronic studies have also been reported for  metal complexes.  Electronic spectra and magnetic susceptibility  measurements suggested tetrahedral geometry for Ni(II) (3), square  planar geometry for Cu(II) (4) complexes of 1, and octahedral  geometries for both Ni(II) (5) and Cu(II) (6) complexes of 2.

 

The novel phenolic Mannich bases 2,2'-(2-hydroxy-4,5-  dimethylbenzylazanediyl)diethanol (1) and 2-((2-(4-(2-hydroxy-4,5-  dimethylbenzyl)piperazin-1-yl)ethylamino)methyl)-4,5-dimethylphenol  (2) have been synthesized in good yield by using a microwave-induced  technique from 3,4-dimethylphenol and corresponding amines in the  presence of formaldehyde.  Metal complexes of 1 and 2 for Ni(II) (3  and 5) and for Cu(II) (4 and 6) have also been prepared and all  compounds have been characterized by elemental and spectral analyses.  Thermal, magnetic, and electronic studies have also been reported for  metal complexes.  Electronic spectra and magnetic susceptibility  measurements suggested tetrahedral geometry for Ni(II) (3), square  planar geometry for Cu(II) (4) complexes of 1, and octahedral  geometries for both Ni(II) (5) and Cu(II) (6) complexes of 2.

Makale detayları

Synthesis and characterization of Ni(II) and Cu(II) complexes derived from novel phenolic Mannich bases

Yazarlar: Nurgün BÜYÜKKIDAN | Salih ÖZER

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2013 Vol.37 Issue 1, pp.101-110

Belge Tipi: Makale

Yayın Tarihi: 12/2012

Belge Dili: Türkçe

Document ID (Org No.): 2000727494

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Nurgün BÜYÜKKIDAN | Salih ÖZER

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2013 Vol.37 Issue 1, pp.101-110

Belge Tipi:

Makale

Yayın Tarihi:

12/2012

Belge Dili:

Türkçe

Document ID (Org No.):

2000727494

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527