2D MAXY--JRES NMR Spectroscopy of CHnCHm (CAnCXm) Groups: Product Operator Theory and Simulation

İrfan ŞAKA; Sedat GÜMÜŞ and Azmi GENÇTEN

Makale detayları

2D MAXY--JRES NMR Spectroscopy of CHnCHm (CAnCXm) Groups: Product Operator Theory and Simulation

Yazarlar:

İrfan ŞAKA | Sedat GÜMÜŞ and Azmi GENÇTEN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Physics 2007 Vol.31 Issue 6, pp.347-354

Belge Tipi:

Makale

Yayın Tarihi:

5/2007

Belge Dili:

Türkçe

Document ID (Org No.):

2000761080

Sıklık:

İki Aylık

eISSN:

1303-6122

pISSN:

1300-0101

Anahtar kelimeler:

Özet:

 

There exist a variety of multi-pulse NMR experiments for  spectral editing of complex molecules in solution.  Maximum quantum  correlation NMR spectroscopy (MAXY NMR) is one of the techniques for  distinguishing CHn groups by editing 1H NMR spectra.  Spectral  assignments of 2D homonuclear J-resolved NMR spectroscopy become too  difficult, due to complex overlapping spectra.  In order to overcome  this problem a new technique called 2D MAXY-JRES NMR spectroscopy,  which is the combination of MAXY NMR and homonuclear J-resolved NMR  spectroscopy techniques, is used.  In this study, product operator  theory of 2D MAXY-JRES NMR spectroscopy is performed for ISn I'S'm  (I = I' = S = S' = 1\2; n = 1, 2; m = 1,2,3) multi-spin systems.  By  using obtained theoretical results, simulated spectra of 2D MAXY-JRES  NMR spectroscopy are presented for several CHnCHm (CAnCXm) groups.

 

There exist a variety of multi-pulse NMR experiments for  spectral editing of complex molecules in solution.  Maximum quantum  correlation NMR spectroscopy (MAXY NMR) is one of the techniques for  distinguishing CHn groups by editing 1H NMR spectra.  Spectral  assignments of 2D homonuclear J-resolved NMR spectroscopy become too  difficult, due to complex overlapping spectra.  In order to overcome  this problem a new technique called 2D MAXY-JRES NMR spectroscopy,  which is the combination of MAXY NMR and homonuclear J-resolved NMR  spectroscopy techniques, is used.  In this study, product operator  theory of 2D MAXY-JRES NMR spectroscopy is performed for ISn I'S'm  (I = I' = S = S' = 1\2; n = 1, 2; m = 1,2,3) multi-spin systems.  By  using obtained theoretical results, simulated spectra of 2D MAXY-JRES  NMR spectroscopy are presented for several CHnCHm (CAnCXm) groups.

Makale detayları

2D MAXY--JRES NMR Spectroscopy of CHnCHm (CAnCXm) Groups: Product Operator Theory and Simulation

Yazarlar:

İrfan ŞAKA | Sedat GÜMÜŞ and Azmi GENÇTEN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Physics 2007 Vol.31 Issue 6, pp.347-354

Belge Tipi:

Makale

Yayın Tarihi:

5/2007

Belge Dili:

Türkçe

Document ID (Org No.):

2000761080

Sıklık:

İki Aylık

eISSN:

1303-6122

pISSN:

1300-0101

NMR

MAXY-JRES

product operator formalism

multi-spin systems

Sayı

Makale detayları

2D MAXY--JRES NMR Spectroscopy of CHnCHm (CAnCXm) Groups: Product Operator Theory and Simulation

Yazarlar: İrfan ŞAKA | Sedat GÜMÜŞ and Azmi GENÇTEN

Yayıncı: TUBITAK

Dergi: Turkish Journal of Physics 2007 Vol.31 Issue 6, pp.347-354

Belge Tipi: Makale

Yayın Tarihi: 5/2007

Belge Dili: Türkçe

Document ID (Org No.): 2000761080

Sıklık: İki Aylık

eISSN: 1303-6122

pISSN: 1300-0101

NMR

MAXY-JRES

product operator formalism

multi-spin systems

Sayı

Yazarlar:

İrfan ŞAKA | Sedat GÜMÜŞ and Azmi GENÇTEN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Physics 2007 Vol.31 Issue 6, pp.347-354

Belge Tipi:

Makale

Yayın Tarihi:

5/2007

Belge Dili:

Türkçe

Document ID (Org No.):

2000761080

Sıklık:

İki Aylık

eISSN:

1303-6122

pISSN:

1300-0101