Syntheses and characterization of new dithiophosphinato zinc complexes

Ertuğrul Gazi SAĞLAM; Nurcan ACAR

doi:https://doi.org/10.18596/jotcsa.427192

Makale detayları

Syntheses and characterization of new dithiophosphinato zinc complexes

Yazarlar:

Ertuğrul Gazi SAĞLAM | Nurcan ACAR

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 2, pp.931-940

Belge Tipi:

Makale

Yayın Tarihi:

12/2017

Belge Dili:

İngilizce

Document ID (Org No.):

2000503273

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.427192

Özet:

 

Four known dithiophosphinic
acids, DTPA, were synthesized and their zinc complexes were prepared as
novelties. The complexes have been proven to have the structures [Zn(µ-DTPAn)2(DTPAn)2],
([DTPAn]= Rn(R)P(S)H, R= 4-CH3O-C6H4-;
R1= iso-amyl-, DTPA1; R2= iso-butyl-,
DTPA2; R3= sec-butyl-, DTPA3; R4=
iso-propyl-, DTPA4). The DTPAs were prepared by the reaction
of the Lawesson
reagent, [2,4–bis(4-methoxyphenyl)–1,3,2,4–ditiyodifosfetan–2,4–disülfür] (LR),
with the corresponding Grignard compounds. The acids formed are viscous liquids
difficult to purify and so they were converted to ammonium salts, [DTPAn][NH4],
which are easy to obtain as pure crystals. The complexes were identified to
have dimeric structures on the basis of mass spectroscopic data.

Makale detayları

Syntheses and characterization of new dithiophosphinato zinc complexes

Yazarlar: Ertuğrul Gazi SAĞLAM | Nurcan ACAR

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Kimya mühendisliği

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 2, pp.931-940

Belge Tipi: Makale

Yayın Tarihi: 12/2017

Belge Dili: İngilizce

Document ID (Org No.): 2000503273

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.427192

Sayı

Yazarlar:

Ertuğrul Gazi SAĞLAM | Nurcan ACAR

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 2, pp.931-940

Belge Tipi:

Makale

Yayın Tarihi:

12/2017

Belge Dili:

İngilizce

Document ID (Org No.):

2000503273

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.427192