Syntheses and spectroscopic investigations of  2-pyridyl(N/N)spirocyclotriphosphazenes

Gamze ELMAS

doi:https://doi.org/10.18596/jotcsa.379971

Makale detayları

Syntheses and spectroscopic investigations of 2-pyridyl(N/N)spirocyclotriphosphazenes

Yazarlar:

Gamze ELMAS

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 2, pp.621-634

Belge Tipi:

Makale

Yayın Tarihi:

12/2017

Belge Dili:

İngilizce

Document ID (Org No.):

2000503184

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.379971

Özet:

 


The Cl substitution reaction of N3P3Cl6
(1) with N-(2-pyridyl)-methyl-N'-methylpropane-1,3-diamine
(2) afforded the partly substituted 2-pyridyl(N/N)spirocyclotriphosphazene
(3) (with a yield of 57%) in dry THF.
When the Cl replacement reactions of 2 carried
out with
excess pyrrolidine, morpholine and 1,4-dioxa-8-azaspiro[4,5]decane (DASD), the corresponding 2-pyridyl(N/N)spirotetrapyrrolidino (3a),
tetramorpholino (3b) and tetra(1,4-dioxa-8-azaspiro[4,5]decano) (3c) cyclotriphosphazenes were prepared in moderate
yields. The structures of four cyclotriphosphazene
derivatives were elucidated by the elemental
analyses, Fourier transform infrared (FTIR),
heteronuclear mass spectrometry (ESI-MS), heteronuclear multiple-bond
correlation (HMBC), single quantum coherence (HSQC), 1H, 13C,
and 31P NMR techniques.


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Makale detayları

Syntheses and spectroscopic investigations of 2-pyridyl(N/N)spirocyclotriphosphazenes

Yazarlar: Gamze ELMAS

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Kimya mühendisliği

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 2, pp.621-634

Belge Tipi: Makale

Yayın Tarihi: 12/2017

Belge Dili: İngilizce

Document ID (Org No.): 2000503184

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.379971

Sayı

Yazarlar:

Gamze ELMAS

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 2, pp.621-634

Belge Tipi:

Makale

Yayın Tarihi:

12/2017

Belge Dili:

İngilizce

Document ID (Org No.):

2000503184

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.379971