Microwave-assisted synthesis and characterization of Co(II) phthalocyanine and investigation of its catalytic activity on 4-nitrophenol oxidation

Ece Tuğba SAKA; Zekeriya BIYIKLIOĞLU; Halit KANTEKİN

Makale detayları

Microwave-assisted synthesis and characterization of Co(II) phthalocyanine and investigation of its catalytic activity on 4-nitrophenol oxidation

Yazarlar:

Ece Tuğba SAKA | Zekeriya BIYIKLIOĞLU | Halit KANTEKİN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2014 Vol.38 Issue 6, pp.1166-1173

Belge Tipi:

Makale

Yayın Tarihi:

5/2014

Belge Dili:

Türkçe

Document ID (Org No.):

2000727044

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

In this study, new cobalt phthalocyanine containing a 2-(2-benzothiazolylthio)ethoxy group at peripheral positions has been synthesized and characterized by spectroscopic methods (IR, UV-Vis elemental analysis, and mass spectroscopies). Catalytic activity of Co(II) phthalocyanine has been investigated in the presence of oxidants such as tert-buthylhydroperoxide, m-chloroperoxybenzoic acid, and H2O2. Co(II) phthalocyanine shows catalytically activity and product conversion under mild conditions. To find the optimal conditions in the oxidation process, substrate ratio, oxidant ratio, temperature, and oxidant type were examined over 3 h. The results exhibit the best optimum reaction conditions in this catalytic system.

 

In this study, new cobalt phthalocyanine containing a 2-(2-benzothiazolylthio)ethoxy group at peripheral positions has been synthesized and characterized by spectroscopic methods (IR, UV-Vis elemental analysis, and mass spectroscopies). Catalytic activity of Co(II) phthalocyanine has been investigated in the presence of oxidants such as tert-buthylhydroperoxide, m-chloroperoxybenzoic acid, and H2O2. Co(II) phthalocyanine shows catalytically activity and product conversion under mild conditions. To find the optimal conditions in the oxidation process, substrate ratio, oxidant ratio, temperature, and oxidant type were examined over 3 h. The results exhibit the best optimum reaction conditions in this catalytic system.

Makale detayları

Microwave-assisted synthesis and characterization of Co(II) phthalocyanine and investigation of its catalytic activity on 4-nitrophenol oxidation

Yazarlar: Ece Tuğba SAKA | Zekeriya BIYIKLIOĞLU | Halit KANTEKİN

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2014 Vol.38 Issue 6, pp.1166-1173

Belge Tipi: Makale

Yayın Tarihi: 5/2014

Belge Dili: Türkçe

Document ID (Org No.): 2000727044

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Ece Tuğba SAKA | Zekeriya BIYIKLIOĞLU | Halit KANTEKİN

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2014 Vol.38 Issue 6, pp.1166-1173

Belge Tipi:

Makale

Yayın Tarihi:

5/2014

Belge Dili:

Türkçe

Document ID (Org No.):

2000727044

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527