A novel Benzimidazole moiety-appended Schiff base derivative: Synthesis, characterization and the investigation of photophysical and chemosensor properties

Pınar ŞEN; Salih Zeki YILDIZ; Necmi DEGE; Göknur Yaşa ATMACA; Ali ERDOĞMUŞ; Mustafa DEGE

doi:https://doi.org/10.18596/jotcsa.478665

Makale detayları

A novel Benzimidazole moiety-appended Schiff base derivative: Synthesis, characterization and the investigation of photophysical and chemosensor properties

Yazarlar:

Pınar ŞEN | Salih Zeki YILDIZ | Necmi DEGE | Göknur Yaşa ATMACA | Ali ERDOĞMUŞ | Mustafa DEGE

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 3, pp.1375-1386

Belge Tipi:

Makale

Yayın Tarihi:

8/2018

Belge Dili:

İngilizce

Document ID (Org No.):

2000503069

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.478665

Özet:

 


In this study, we synthesized a novel
benzimidazole-based Schiff base;
(E)-4,4'-methylenebis(2-((E)-(((1H-benzo[d]imidazol-2-yl)methyl)imino)methyl)phenol)
(3) was synthesized by the
condensation of 5,5'-methylenebis(2-hydroxybenzaldehyde) (1) and (1H-benzo[d]imidazol-2-yl)methanamine.HCl salt (2). This Schiff base derivative was
reported for the first time and was fully characterized by FT-IR, UV–vis, 1H-NMR,
13C-NMR and mass spectroscopy. Electronic absorption and
fluorescence titration studies of 3
with different metal cations in a DMF show a highly selective binding affinity
only toward and Zn2+ ion. The crystal
structure of 2, C8H13Cl2N3O,
has been determined by single crystal X-ray
diffraction method. The crystal structure of the title compound, C8H11N32+×2(Cl—)×H2O, consists of an organic 1H-benzoimidazol-3-ium
(C8H11N32+) cation, an inorganic
2(Cl—) anion and one water (H2O) molecule. In the
cation of the title compound, C8H11N32+,
the benzimidazole ring system  is planar with a maximum deviation of -0.012
(3) Å. The crystal
belongs to monoclinic system, space group P21/c. The crystal packing is stabilized by intramolecular
N–H···O, N–H···Cl, the intermolecular
N–H···Cl interactions link the molecules into a
two-dimensional network and between anions and the water molecules. π-π contacts between benzimidazole rings
[centroid–centroid distances = 3.4642 (2) Å,
3.5309 (2) Å and 3.5527 (2) Å] may further stabilize the structure.



 

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Makale detayları

A novel Benzimidazole moiety-appended Schiff base derivative: Synthesis, characterization and the investigation of photophysical and chemosensor properties

Yazarlar: Pınar ŞEN | Salih Zeki YILDIZ | Necmi DEGE | Göknur Yaşa ATMACA | Ali ERDOĞMUŞ | Mustafa DEGE

Yayıncı: Turkish Chemical Society

Ana Başlıklar: Kimya mühendisliği

Dergi: Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 3, pp.1375-1386

Belge Tipi: Makale

Yayın Tarihi: 8/2018

Belge Dili: İngilizce

Document ID (Org No.): 2000503069

Sıklık: Üç Aylık

eISSN: 2149-0120

DOI: https://doi.org/10.18596/jotcsa.478665

Sayı

Yazarlar:

Pınar ŞEN | Salih Zeki YILDIZ | Necmi DEGE | Göknur Yaşa ATMACA | Ali ERDOĞMUŞ | Mustafa DEGE

Yayıncı:

Turkish Chemical Society

Ana Başlıklar:

Kimya mühendisliği

Dergi:

Journal of the Turkish Chemical Society Section A: Chemistry 2018 Vol.5 Issue 3, pp.1375-1386

Belge Tipi:

Makale

Yayın Tarihi:

8/2018

Belge Dili:

İngilizce

Document ID (Org No.):

2000503069

Sıklık:

Üç Aylık

eISSN:

2149-0120

DOI:

https://doi.org/10.18596/jotcsa.478665