Synthesis and Characterization of 3-Aminomethylpyridine and the Salt of 2,6-Pyridinedicarboxylic Acid and Fe(III), Co(II) and Cu(II) Complexes of the Salt

Hülya Aydın; Halil İlkimen

Makale detayları

Synthesis and Characterization of 3-Aminomethylpyridine and the Salt of 2,6-Pyridinedicarboxylic Acid and Fe(III), Co(II) and Cu(II) Complexes of the Salt

Yazarlar:

Hülya Aydın | Halil İlkimen

Yayıncı:

Bayburt University

Ana Başlıklar:

Kimya Mühendisliği (Diğer)

Dergi:

Bayburt Üniversitesi Fen Bilimleri Dergisi Vol.7 Issue 1, pp.27-34

Belge Tipi:

Makale

Yayın Tarihi:

6/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001320461

pISSN:

2667-579X

Anahtar kelimeler:

Özet:

 In this study, proton transfer salt H3ampHdipic-, 1 between 3-aminomethylpyridine 3amp and 2,6-pyridinedicarboxylic acid H2dipic and it FeIII H3ampFedipic2.2H2O, 2, CoII H3amp2Codipic2.3H2O, 3 and CuII H3amp2Cudipic2.5H2O, 4 were synthesized. Novel compounds were characterized by FT-IR, AAS, NMR 1H and 13C, UV, magnetic, and molar conductivity tests. According to the spectroscopic analysis results, the acid:base ratio is 1:1 for salt, while the metal:acid:base ratio is 1:2:1 for 2 and 1:2:2 for 3 and 4. The structures of all complexes are proposed to be octahedral.

 In this study, proton transfer salt H3ampHdipic-, 1 between 3-aminomethylpyridine 3amp and 2,6-pyridinedicarboxylic acid H2dipic and it FeIII H3ampFedipic2.2H2O, 2, CoII H3amp2Codipic2.3H2O, 3 and CuII H3amp2Cudipic2.5H2O, 4 were synthesized. Novel compounds were characterized by FT-IR, AAS, NMR 1H and 13C, UV, magnetic, and molar conductivity tests. According to the spectroscopic analysis results, the acid:base ratio is 1:1 for salt, while the metal:acid:base ratio is 1:2:1 for 2 and 1:2:2 for 3 and 4. The structures of all complexes are proposed to be octahedral.

 In this study, proton transfer salt H3ampHdipic-, 1 between 3-aminomethylpyridine 3amp and 2,6-pyridinedicarboxylic acid H2dipic and it FeIII H3ampFedipic2.2H2O, 2, CoII H3amp2Codipic2.3H2O, 3 and CuII H3amp2Cudipic2.5H2O, 4 were synthesized. Novel compounds were characterized by FT-IR, AAS, NMR 1H and 13C, UV, magnetic, and molar conductivity tests. According to the spectroscopic analysis results, the acid:base ratio is 1:1 for salt, while the metal:acid:base ratio is 1:2:1 for 2 and 1:2:2 for 3 and 4. The structures of all complexes are proposed to be octahedral.

 Bu çalışmada, 3-aminometilpiridin 3amp ile dipikolinik asitin H2dipic proton transfer tuzu H3ampHdipic-, 1 ve tuzun FeIII H3ampFedipic2.2H2O, 2, CoII H3amp2Codipic2.3H2O, 3 ve CuII H3amp2Cudipic2.5H2O, 4 kompleksleri sentezlenmiştir. Yeni sentezlenen bileşiklerin karakterizasyonu için FT-IR, AAS, NMR 1H ve 13C, UV, manyetik ve molar iletkenlik ölçümleri kullanılmıştır. Spektroskopik analiz sonuçlarına göre asit:baz oranı tuz için 1:1 iken, metal:asit:baz oranı 2 için 1:2:1 ve 3 ve 4 için 1:2:2 dir. Tüm komplekslerin yapıları oktahedral olarak önerilmiştir.

Makale detayları

Synthesis and Characterization of 3-Aminomethylpyridine and the Salt of 2,6-Pyridinedicarboxylic Acid and Fe(III), Co(II) and Cu(II) Complexes of the Salt

Yazarlar:

Hülya Aydın | Halil İlkimen

Yayıncı:

Bayburt University

Ana Başlıklar:

Kimya Mühendisliği (Diğer)

Dergi:

Bayburt Üniversitesi Fen Bilimleri Dergisi Vol.7 Issue 1, pp.27-34

Belge Tipi:

Makale

Yayın Tarihi:

6/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001320461

pISSN:

2667-579X

3-Aminomethylpyridine

Dipicolinic acid

Proton transfer salt

Fe(III) complex

Co(II) complex

Cu(II) complex3-Aminometilpiridin

Dipikolinik asit

Proton transfer tuzu

Fe(III) kompleks

Co(II) kompleks

Cu(II) kompleks

Sayı

Makale detayları

Yazarlar: Hülya Aydın | Halil İlkimen

Yayıncı: Bayburt University

Ana Başlıklar: Kimya Mühendisliği (Diğer)

Dergi: Bayburt Üniversitesi Fen Bilimleri Dergisi Vol.7 Issue 1, pp.27-34

Belge Tipi: Makale

Yayın Tarihi: 6/2024

Belge Dili: Türkçe

Document ID (Org No.): 2001320461

pISSN: 2667-579X

Sayı

Yazarlar:

Hülya Aydın | Halil İlkimen

Yayıncı:

Bayburt University

Ana Başlıklar:

Kimya Mühendisliği (Diğer)

Dergi:

Bayburt Üniversitesi Fen Bilimleri Dergisi Vol.7 Issue 1, pp.27-34

Belge Tipi:

Makale

Yayın Tarihi:

6/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001320461

pISSN:

2667-579X