A New Approach to the Ring Opening Reactions of 2,7,7-Trimethyl-3,3-dibromotricyclo[4.1.1.02,4]octane

Zekir ŞENOL; Ömer ZAİM; Metin BALCI

Makale detayları

A New Approach to the Ring Opening Reactions of 2,7,7-Trimethyl-3,3-dibromotricyclo[4.1.1.02,4]octane

Yazarlar:

Zekir ŞENOL | Ömer ZAİM | Metin BALCI

Yayıncı:

TUBITAK

Ana Başlıklar:

Kimya ve ilgili bilimler

Dergi:

Turkish Journal of Chemistry 2005 Vol.29 Issue 5, pp.531-538

Belge Tipi:

Makale

Yayın Tarihi:

4/2005

Belge Dili:

İngilizce

Document ID (Org No.):

2000729046

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

The reaction of a-pinene and dibromocarbene produced a  fairly unstable product, 2,7,7-trimethyl-3,3-dibromotricyclo[4.1.1.02,4]octane,  from which 3-bromo-7,7-dimethyl-2-methylenebicyclo[4,1,1]oct-3-ene and  3-bromo-2,7,7-trimethylbicyclo [4,1,1]octa-2,4-diene were obtained in  chloroform at room temperature and in various other media and  conditions.  Two new compounds, 3-bromo-2,7,7-trimethylbicyclo  [4.1.1]oct-3-en-2-ol and 2-(4-bromo-5-methylcyclohepta-3,5-dien-1-yl)  propan-2-ol, were observed in aqueous acetone in addition to the  previous two.  The stability and formation mechanism of the formed  products are discussed.

 

The reaction of a-pinene and dibromocarbene produced a  fairly unstable product, 2,7,7-trimethyl-3,3-dibromotricyclo[4.1.1.02,4]octane,  from which 3-bromo-7,7-dimethyl-2-methylenebicyclo[4,1,1]oct-3-ene and  3-bromo-2,7,7-trimethylbicyclo [4,1,1]octa-2,4-diene were obtained in  chloroform at room temperature and in various other media and  conditions.  Two new compounds, 3-bromo-2,7,7-trimethylbicyclo  [4.1.1]oct-3-en-2-ol and 2-(4-bromo-5-methylcyclohepta-3,5-dien-1-yl)  propan-2-ol, were observed in aqueous acetone in addition to the  previous two.  The stability and formation mechanism of the formed  products are discussed.

Makale detayları

A New Approach to the Ring Opening Reactions of 2,7,7-Trimethyl-3,3-dibromotricyclo[4.1.1.02,4]octane

Yazarlar: Zekir ŞENOL | Ömer ZAİM | Metin BALCI

Yayıncı: TUBITAK

Ana Başlıklar: Kimya ve ilgili bilimler

Dergi: Turkish Journal of Chemistry 2005 Vol.29 Issue 5, pp.531-538

Belge Tipi: Makale

Yayın Tarihi: 4/2005

Belge Dili: İngilizce

Document ID (Org No.): 2000729046

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Zekir ŞENOL | Ömer ZAİM | Metin BALCI

Yayıncı:

TUBITAK

Ana Başlıklar:

Kimya ve ilgili bilimler

Dergi:

Turkish Journal of Chemistry 2005 Vol.29 Issue 5, pp.531-538

Belge Tipi:

Makale

Yayın Tarihi:

4/2005

Belge Dili:

İngilizce

Document ID (Org No.):

2000729046

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527