The Synthesis of Substituted 4,40 -Thiobis(Aminophenylglyoxime) and Their Polymeric Metal Complexes with Cu(II), Ni(II) and Co(II) Salts

Ahmet COŞKUN; İbrahim KARATAŞ

Makale detayları

The Synthesis of Substituted 4,40 -Thiobis(Aminophenylglyoxime) and Their Polymeric Metal Complexes with Cu(II), Ni(II) and Co(II) Salts

Yazarlar:

Ahmet COŞKUN | İbrahim KARATAŞ

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2004 Vol.28 Issue 2, pp.173-180

Belge Tipi:

Makale

Yayın Tarihi:

1/2004

Belge Dili:

İngilizce

Document ID (Org No.):

2000729367

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

4,4'-Bis(chloroacetyl)diphenyl thioether (HL) was  synthesized from chloroacetyl chloride and diphenyl thioether in the  presence of AlCl3 as catalyst in a Friedel-Crafts reaction.   Subsequently, its keto oxime (H2L) and glyoxime (H4L) derivatives  were also prepared.  Then 3 new substituted 4,4'-thiobis(aminophen-  ylglyoxime) (H4L1 - 3) were synthesized from  4,4'-thiobis(chlorophenylglyoxime) and the corresponding amines.  The  Ni(II), Cu(II) and Co(II) complexes of these ligands were prepared.   The structures of these ligands and their complexes were identifed by  FT-IR, 1H NMR and ICP-AES spectral data, elemental analyses and  magnetic measurements.

 

4,4'-Bis(chloroacetyl)diphenyl thioether (HL) was  synthesized from chloroacetyl chloride and diphenyl thioether in the  presence of AlCl3 as catalyst in a Friedel-Crafts reaction.   Subsequently, its keto oxime (H2L) and glyoxime (H4L) derivatives  were also prepared.  Then 3 new substituted 4,4'-thiobis(aminophen-  ylglyoxime) (H4L1 - 3) were synthesized from  4,4'-thiobis(chlorophenylglyoxime) and the corresponding amines.  The  Ni(II), Cu(II) and Co(II) complexes of these ligands were prepared.   The structures of these ligands and their complexes were identifed by  FT-IR, 1H NMR and ICP-AES spectral data, elemental analyses and  magnetic measurements.

Makale detayları

The Synthesis of Substituted 4,40 -Thiobis(Aminophenylglyoxime) and Their Polymeric Metal Complexes with Cu(II), Ni(II) and Co(II) Salts

Yazarlar: Ahmet COŞKUN | İbrahim KARATAŞ

Yayıncı: TUBITAK

Ana Başlıklar: Uygulamalı fizik

Dergi: Turkish Journal of Chemistry 2004 Vol.28 Issue 2, pp.173-180

Belge Tipi: Makale

Yayın Tarihi: 1/2004

Belge Dili: İngilizce

Document ID (Org No.): 2000729367

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

Ahmet COŞKUN | İbrahim KARATAŞ

Yayıncı:

TUBITAK

Ana Başlıklar:

Uygulamalı fizik

Dergi:

Turkish Journal of Chemistry 2004 Vol.28 Issue 2, pp.173-180

Belge Tipi:

Makale

Yayın Tarihi:

1/2004

Belge Dili:

İngilizce

Document ID (Org No.):

2000729367

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527