Synthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes

İlknur BABAHAN; Hüseyin ANIL; Nursabah SARIKAVAKLI

Makale detayları

Synthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes

Yazarlar:

İlknur BABAHAN | Hüseyin ANIL | Nursabah SARIKAVAKLI

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2011 Vol.35 Issue 4, pp.613-624

Belge Tipi:

Makale

Yayın Tarihi:

3/2011

Belge Dili:

Türkçe

Document ID (Org No.):

2000727801

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527

Özet:

 

In this study, the synthesis of a novel tetraoxime (LH4)  derivative containing hydrazone side groups, and its transition metal  complexes with Ni(II), Cu(II), Co(II), and Zn(II) ions, were reported.  The ligand was synthesized by reacting anti-glyoximehydrazine (GH2)  with terephthaldialdehyde.  Polymeric complexes with Ni(II) and Co(II)  and binuclear complexes with Cu(II) and Zn(II) of this tetraoxime were  isolated.  Structural assignments were supported by a combination of  1H-NMR, 13C-NMR, HMQC, FT-IR, UV-Vis, thermogravimetric analysis  (TGA), molar conductances, elemental analyses, and magnetic  susceptibility.

 

In this study, the synthesis of a novel tetraoxime (LH4)  derivative containing hydrazone side groups, and its transition metal  complexes with Ni(II), Cu(II), Co(II), and Zn(II) ions, were reported.  The ligand was synthesized by reacting anti-glyoximehydrazine (GH2)  with terephthaldialdehyde.  Polymeric complexes with Ni(II) and Co(II)  and binuclear complexes with Cu(II) and Zn(II) of this tetraoxime were  isolated.  Structural assignments were supported by a combination of  1H-NMR, 13C-NMR, HMQC, FT-IR, UV-Vis, thermogravimetric analysis  (TGA), molar conductances, elemental analyses, and magnetic  susceptibility.

Makale detayları

Synthesis of novel tetraoxime derivative with hydrazone side groups and its metal complexes

Yazarlar: İlknur BABAHAN | Hüseyin ANIL | Nursabah SARIKAVAKLI

Yayıncı: TUBITAK

Dergi: Turkish Journal of Chemistry 2011 Vol.35 Issue 4, pp.613-624

Belge Tipi: Makale

Yayın Tarihi: 3/2011

Belge Dili: Türkçe

Document ID (Org No.): 2000727801

Sıklık: İki Aylık

eISSN: 1303-6130

pISSN: 1300-0527

Sayı

Yazarlar:

İlknur BABAHAN | Hüseyin ANIL | Nursabah SARIKAVAKLI

Yayıncı:

TUBITAK

Dergi:

Turkish Journal of Chemistry 2011 Vol.35 Issue 4, pp.613-624

Belge Tipi:

Makale

Yayın Tarihi:

3/2011

Belge Dili:

Türkçe

Document ID (Org No.):

2000727801

Sıklık:

İki Aylık

eISSN:

1303-6130

pISSN:

1300-0527