Study on Interaction Capabilities of Ternary Liquid Mixtures by  Thermodynamic Parameters at 308.15 K

Uma Sivakami KRİSHNAMOORTHY; Vaideeswaran SUNDARRAJAN; Rosevenis AMBROSE; K. SHENBAGAM

doi:https://doi.org/10.5541/ijot.1010582

Makale detayları

Study on Interaction Capabilities of Ternary Liquid Mixtures by Thermodynamic Parameters at 308.15 K

Yazarlar:

Uma Sivakami KRİSHNAMOORTHY | Vaideeswaran SUNDARRAJAN | Rosevenis AMBROSE | K. SHENBAGAM

Yayıncı:

Uluslararası Uygulamalı Termodinamik Derneği İktisadi İşletmesi

Ana Başlıklar:

Fiziksel ve teorik kimya

Dergi:

International Journal of Thermodynamics 2022 Vol.25 Issue 2, pp.40-48

Belge Tipi:

Makale

Yayın Tarihi:

5/2022

Belge Dili:

İngilizce

Document ID (Org No.):

2000476451

Sıklık:

Üç Aylık

eISSN:

2146-1511

pISSN:

1301-9724

DOI:

https://doi.org/10.5541/ijot.1010582

Özet:

 

Thermodynamic properties provide a deep and significant insight of the various interactions taking place multi component liquid mixtures especially in the field of petrochemical and reservoir engineering. The density, viscosity and ultrasonic velocity were measured experimentally for diethylmalonate (DEM) +1,4-dioxane with nitrobenzene (TM-1) and diethylmalonate (DEM) +1,4-dioxane + toluene (TM-2) at the temperature of 308.15K and atmospheric pressure over the entire range of mole fraction.  The excess thermodynamic properties such as excess volume (VE), excess adiabatic compressibility (ΔKs), excess viscosity (Δɳ), excess free volume (ΔVF), excess free length (ΔLF), excess isothermal compressibility (ΔβΤ), were calculated from measured values and applied to Redlich - Kister polynomial equation to determine the appropriate coefficients. The excess or deviation properties were found to be either negative or positive depending on the molecular interactions and the nature of liquid mixtures. The deviations of the ternary mixtures from its ideal behaviour were determined in order to investigate the molecular interaction between the components of ternary liquid mixtures.

Makale detayları

Study on Interaction Capabilities of Ternary Liquid Mixtures by Thermodynamic Parameters at 308.15 K

Yazarlar: Uma Sivakami KRİSHNAMOORTHY | Vaideeswaran SUNDARRAJAN | Rosevenis AMBROSE | K. SHENBAGAM

Yayıncı: Uluslararası Uygulamalı Termodinamik Derneği İktisadi İşletmesi

Ana Başlıklar: Fiziksel ve teorik kimya

Dergi: International Journal of Thermodynamics 2022 Vol.25 Issue 2, pp.40-48

Belge Tipi: Makale

Yayın Tarihi: 5/2022

Belge Dili: İngilizce

Document ID (Org No.): 2000476451

Sıklık: Üç Aylık

eISSN: 2146-1511

pISSN: 1301-9724

DOI: https://doi.org/10.5541/ijot.1010582

Sayı

Yazarlar:

Uma Sivakami KRİSHNAMOORTHY | Vaideeswaran SUNDARRAJAN | Rosevenis AMBROSE | K. SHENBAGAM

Yayıncı:

Uluslararası Uygulamalı Termodinamik Derneği İktisadi İşletmesi

Ana Başlıklar:

Fiziksel ve teorik kimya

Dergi:

International Journal of Thermodynamics 2022 Vol.25 Issue 2, pp.40-48

Belge Tipi:

Makale

Yayın Tarihi:

5/2022

Belge Dili:

İngilizce

Document ID (Org No.):

2000476451

Sıklık:

Üç Aylık

eISSN:

2146-1511

pISSN:

1301-9724

DOI:

https://doi.org/10.5541/ijot.1010582