Solubility and Phase Equilibrium of Na+, Mn++/ H2PO2-, Cl-//H2O Ternary System at 323K

Vedat Adıgüzel; Sevilay Demirci; Hasan Erge; Ali Rıza Kul

Makale detayları

Solubility and Phase Equilibrium of Na+, Mn++/ H2PO2-, Cl-//H2O Ternary System at 323K

Yazarlar:

Vedat Adıgüzel | Sevilay Demirci | Hasan Erge | Ali Rıza Kul

Yayıncı:

Kafkas University

Ana Başlıklar:

Analitik Kimya (Diğer)

Dergi:

Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.17 Issue 2, pp.75-80

Belge Tipi:

Makale

Yayın Tarihi:

12/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001335197

pISSN:

2587-2389

Anahtar kelimeler:

Özet:

 In this study, the density and phase changes of MnH2PO22 and NaCl in aqueous medium were investigated. All experiments were carried out under atmospheric pressure. It was observed that the studied ternary system was in accordance with the simple eutonic point system, that is, a certain ratio of the component in the mixture system, the components solidify together at the point where the system has the lowest freezing point and there is a phase change at a single temperature and it does not contain any binary salt. The solubility and density values of the MnH2PO22-H2O and NaCl-H2O binary systems, which are subsystems of the H2O- MnH2PO22-NaCl system, were determined as 11.14  MnH2PO22 and 26.86  NaCl, 1067 kgm3 and 1189 kgm3 at 323 K, respectively. The eutonic point composition of the composition was determined to contain 24.46 NaCl and 6.02  MnH2PO22 and its density was determined to be 1279 kgm3.

 In this study, the density and phase changes of MnH2PO22 and NaCl in aqueous medium were investigated. All experiments were carried out under atmospheric pressure. It was observed that the studied ternary system was in accordance with the simple eutonic point system, that is, a certain ratio of the component in the mixture system, the components solidify together at the point where the system has the lowest freezing point and there is a phase change at a single temperature and it does not contain any binary salt. The solubility and density values of the MnH2PO22-H2O and NaCl-H2O binary systems, which are subsystems of the H2O- MnH2PO22-NaCl system, were determined as 11.14  MnH2PO22 and 26.86  NaCl, 1067 kgm3 and 1189 kgm3 at 323 K, respectively. The eutonic point composition of the composition was determined to contain 24.46 NaCl and 6.02  MnH2PO22 and its density was determined to be 1279 kgm3.

 In this study, the density and phase changes of MnH2PO22 and NaCl in aqueous medium were investigated. All experiments were carried out under atmospheric pressure. It was observed that the studied ternary system was in accordance with the simple eutonic point system, that is, a certain ratio of the component in the mixture system, the components solidify together at the point where the system has the lowest freezing point and there is a phase change at a single temperature and it does not contain any binary salt. The solubility and density values of the MnH2PO22-H2O and NaCl-H2O binary systems, which are subsystems of the H2O- MnH2PO22-NaCl system, were determined as 11.14  MnH2PO22 and 26.86  NaCl, 1067 kgm3 and 1189 kgm3 at 323 K, respectively. The eutonic point composition of the composition was determined to contain 24.46 NaCl and 6.02  MnH2PO22 and its density was determined to be 1279 kgm3.

 Bu çalışmada, MnH2PO22 ve NaClün sulu ortamda yoğunluk ve faz dengesi üzerine değerlendirilmesi araştırılmıştır. Tüm deneyler atmosferik basıncı altında gerçekleştirildi. Çalışılan üçlü sistemin basit ötonik nokta sistemine uygun yani karışım sisteminde bileşenin belirli bir oranı, sistemin en düşük donma noktasına sahip olduğu noktada bileşenler birlikte katılaşır ve tek bir sıcaklıkta faz değişimi olduğu ve herhangi bir ikili tuz barındırmadığı görülmüştür. H2O- MnH2PO22-NaCl sisteminin alt sistemleri olan MnH2PO22-H2O ve NaCl-H2O ikili sistemlerinin çözünürlük ve yoğunluk değerleri 323 Kde sırasıyla 11,14 MnH2PO22 ve 26.86 NaCl, 1067 kgm3 ve 1189 kgm3 olarak tespit edildi. Bileşimin ötonik nokta bileşimi ise  24.46 NaCl ve  6.02 MnH2PO22 içerdiği ve yoğunluğunun 1279 kgm3 olduğu tespit edilmiştir.

Makale detayları

Solubility and Phase Equilibrium of Na+, Mn++/ H2PO2-, Cl-//H2O Ternary System at 323K

Yazarlar:

Vedat Adıgüzel | Sevilay Demirci | Hasan Erge | Ali Rıza Kul

Yayıncı:

Kafkas University

Ana Başlıklar:

Analitik Kimya (Diğer)

Dergi:

Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.17 Issue 2, pp.75-80

Belge Tipi:

Makale

Yayın Tarihi:

12/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001335197

pISSN:

2587-2389

Hypophosphite

Density

phase equilibria

solubility

Eutonic pointHipofosfit

Yoğunluk

Faz dengesi

Çözünürlük

Ötonik nokta

Sayı

Makale detayları

Yazarlar: Vedat Adıgüzel | Sevilay Demirci | Hasan Erge | Ali Rıza Kul

Yayıncı: Kafkas University

Ana Başlıklar: Analitik Kimya (Diğer)

Dergi: Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.17 Issue 2, pp.75-80

Belge Tipi: Makale

Yayın Tarihi: 12/2024

Belge Dili: Türkçe

Document ID (Org No.): 2001335197

pISSN: 2587-2389

Sayı

Yazarlar:

Vedat Adıgüzel | Sevilay Demirci | Hasan Erge | Ali Rıza Kul

Yayıncı:

Kafkas University

Ana Başlıklar:

Analitik Kimya (Diğer)

Dergi:

Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi Vol.17 Issue 2, pp.75-80

Belge Tipi:

Makale

Yayın Tarihi:

12/2024

Belge Dili:

Türkçe

Document ID (Org No.):

2001335197

pISSN:

2587-2389